Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Yasuo Matsubara, Sean E. Hightower, Jinzhu Chen, David C. Grills, Dmitry E. Polyansky, James T. Muckerman, Koji Tanaka, Etsuko Fujita

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

Original languageEnglish
Pages (from-to)728-730
Number of pages3
JournalChemical Communications
Volume50
Issue number6
DOIs
Publication statusPublished - Dec 12 2014

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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