Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Yasuo Matsubara; Sean E. Hightower; Jinzhu Chen; David C. Grills; Dmitry E. Polyansky; James T. Muckerman; Koji Tanaka; Etsuko Fujita

doi:10.1039/c3cc47699e

Reactivity of a fac-ReCl(α-diimine)(CO)₃ complex with an NAD⁺ model ligand toward CO₂ reduction

Yasuo Matsubara, Sean E. Hightower, Jinzhu Chen, David C. Grills, Dmitry E. Polyansky, James T. Muckerman, Koji Tanaka, Etsuko Fujita

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The reactivity of a rhenium complex containing an NAD⁺ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO₂ reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph₃C⁺.

Original language	English
Pages (from-to)	728-730
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	6
DOIs	https://doi.org/10.1039/c3cc47699e
Publication status	Published - Dec 12 2014

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Reactivity of a fac-ReCl(α-diimine)(CO)₃ complex with an NAD⁺ model ligand toward CO₂ reduction. / Matsubara, Yasuo; Hightower, Sean E.; Chen, Jinzhu; Grills, David C.; Polyansky, Dmitry E.; Muckerman, James T.; Tanaka, Koji; Fujita, Etsuko.

In: Chemical Communications, Vol. 50, No. 6, 12.12.2014, p. 728-730.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.",

author = "Yasuo Matsubara and Hightower, {Sean E.} and Jinzhu Chen and Grills, {David C.} and Polyansky, {Dmitry E.} and Muckerman, {James T.} and Koji Tanaka and Etsuko Fujita",

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AU - Matsubara, Yasuo

AU - Hightower, Sean E.

AU - Chen, Jinzhu

AU - Grills, David C.

AU - Polyansky, Dmitry E.

AU - Muckerman, James T.

AU - Tanaka, Koji

AU - Fujita, Etsuko

PY - 2014/12/12

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N2 - The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

AB - The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

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Reactivity of a fac-ReCl(α-diimine)(CO)₃ complex with an NAD⁺ model ligand toward CO₂ reduction

Abstract

ASJC Scopus subject areas

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