Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Yasuo Matsubara, Sean E. Hightower, Jinzhu Chen, David C. Grills, Dmitry E. Polyansky, James T. Muckerman, Koji Tanaka, Etsuko Fujita

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)


The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

Original languageEnglish
Pages (from-to)728-730
Number of pages3
JournalChemical Communications
Issue number6
Publication statusPublished - Dec 12 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Reactivity of a fac-ReCl(α-diimine)(CO)<sub>3</sub> complex with an NAD<sup>+</sup> model ligand toward CO<sub>2</sub> reduction'. Together they form a unique fingerprint.

Cite this