Abstract
The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.
| Original language | English |
|---|---|
| Pages (from-to) | 728-730 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Dec 12 2014 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Matsubara, Y., Hightower, S. E., Chen, J., Grills, D. C., Polyansky, D. E., Muckerman, J. T., Tanaka, K., & Fujita, E. (2014). Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction. Chemical Communications, 50(6), 728-730. https://doi.org/10.1039/c3cc47699e