Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Yasuo Matsubara; Sean E. Hightower; Jinzhu Chen; David C. Grills; Dmitry E. Polyansky; James T. Muckerman; Koji Tanaka; Etsuko Fujita

doi:10.1039/c3cc47699e

Reactivity of a fac-ReCl(α-diimine)(CO)₃ complex with an NAD⁺ model ligand toward CO₂ reduction

Yasuo Matsubara, Sean E. Hightower, Jinzhu Chen, David C. Grills, Dmitry E. Polyansky, James T. Muckerman, Koji Tanaka, Etsuko Fujita

Brookhaven National Laboratory

Research output: Contribution to journal › Article

16 Citations (Scopus)

Abstract

The reactivity of a rhenium complex containing an NAD⁺ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO₂ reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph₃C⁺.

Original language	English
Pages (from-to)	728-730
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	6
DOIs	https://doi.org/10.1039/c3cc47699e
Publication status	Published - Dec 12 2014

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Matsubara, Y., Hightower, S. E., Chen, J., Grills, D. C., Polyansky, D. E., Muckerman, J. T., Tanaka, K., & Fujita, E. (2014). Reactivity of a fac-ReCl(α-diimine)(CO)₃ complex with an NAD⁺ model ligand toward CO₂ reduction. Chemical Communications, 50(6), 728-730. https://doi.org/10.1039/c3cc47699e

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AU - Polyansky, Dmitry E.

AU - Muckerman, James T.

AU - Tanaka, Koji

AU - Fujita, Etsuko

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10.1039/c3cc47699e