Recent advances in alkane dehydrogenation catalyzed by pincer complexes

Akshai Kumar, Alan S. Goldman

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Olefins are ubiquitous intermediates in the production of fuels and commodity chemicals. Accordingly, the development of methods for the selective dehydrogenation of alkanes to give olefins is a goal with great potential value. Molecular (homogeneous) catalysts appear quite promising in this respect. Great advances have been seen with pincer-ligated catalysts since the mid-1990s, particularly (but not exclusively) with iridium complexes. In this chapter we give an overview of this productive area of research, with emphasis on recent progress.

Original languageEnglish
Pages (from-to)307-334
Number of pages28
JournalTopics in Organometallic Chemistry
Volume54
DOIs
Publication statusPublished - Jan 1 2015

Keywords

  • Alkane functionalization
  • Alkane metathesis
  • Alkylarenes
  • C-H bond activation
  • Dehydrogenation
  • Pincer catalysts

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry
  • Inorganic Chemistry

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