Recent advances in alkane dehydrogenation catalyzed by pincer complexes

Akshai Kumar, Alan S Goldman

Research output: Chapter in Book/Report/Conference proceedingChapter

7 Citations (Scopus)

Abstract

Olefins are ubiquitous intermediates in the production of fuels and commodity chemicals. Accordingly, the development of methods for the selective dehydrogenation of alkanes to give olefins is a goal with great potential value. Molecular (homogeneous) catalysts appear quite promising in this respect. Great advances have been seen with pincer-ligated catalysts since the mid-1990s, particularly (but not exclusively) with iridium complexes. In this chapter we give an overview of this productive area of research, with emphasis on recent progress.

Original languageEnglish
Title of host publicationThe Privileged Pincer-Metal Platform: Coordination Chemistry & Applications
PublisherSpringer International Publishing
Pages307-334
Number of pages28
ISBN (Print)9783319229270, 9783319229263
DOIs
Publication statusPublished - Aug 27 2015

Keywords

  • Alkane functionalization
  • Alkane metathesis
  • Alkylarenes
  • C-H bond activation
  • Dehydrogenation
  • Pincer catalysts

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Engineering(all)

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  • Cite this

    Kumar, A., & Goldman, A. S. (2015). Recent advances in alkane dehydrogenation catalyzed by pincer complexes. In The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications (pp. 307-334). Springer International Publishing. https://doi.org/10.1007/3418_2015_113