Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas

Teddy Asefa, Geoffrey A. Ozin, Hiltrud Grondey, Michal Kruk, Mietek Jaroniec

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Synthetic routes have recently been developed to an entirely new class of organic-inorganic hybrid nanocomposite materials called periodic mesoporous organosilicas (PMOs) containing bridging organic groups integrated within a well-ordered mesoporous silica-based framework structure. Some of the interesting properties of these types of materials have been demonstrated but real challenges still remain including the scope of the synthesis approach and breadth of the compositional domain, reactivity and stability of the materials, their chemical and physical, electrical and mechanical properties, as well as potential applications. In this review, we will describe our past and current research concerning new synthetic strategies, unique properties and advantageous features of alkane, alkylene, aromatic, heteroatom-containing, chiral, and star-like organic functional group containing PMOs as advanced materials for diverse applications. Some of the effects of size and kind of organic groups on the order and integrity of the structure of the materials are discussed. Various synthetic routes, such as lithiation, Grignard, hydroboration, Pd-catalysed Heck coupling and alcoholysis reactions that we used to make the molecular poly(trialkoxysilyl)organic precursors are also briefly described.

Original languageEnglish
Pages (from-to)1-26
Number of pages26
JournalStudies in Surface Science and Catalysis
Volume141
Publication statusPublished - 2002

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chemistry
synthesis
routes
hydroboration
integrity
alkanes
Alkanes
Hybrid materials
nanocomposites
reactivity
physical properties
electrical properties
Silicon Dioxide
mechanical properties
Paraffins
Functional groups
silicon dioxide
Stars
stars
Nanocomposites

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas. / Asefa, Teddy; Ozin, Geoffrey A.; Grondey, Hiltrud; Kruk, Michal; Jaroniec, Mietek.

In: Studies in Surface Science and Catalysis, Vol. 141, 2002, p. 1-26.

Research output: Contribution to journalArticle

Asefa, Teddy ; Ozin, Geoffrey A. ; Grondey, Hiltrud ; Kruk, Michal ; Jaroniec, Mietek. / Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas. In: Studies in Surface Science and Catalysis. 2002 ; Vol. 141. pp. 1-26.
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