Abstract
(Chemical Equation Presented) Unequal partners: One-electron reduction of a pincer-type palladium complex 1 results in collapse of the pincer system and formation of a novel bimetallic diamagnetic complex containing a linearly coordinated 14 e Pd0 center and a non-planar PdII unit (2). The reaction is reversed by oxidation with Ag+ or organic halides. The catalytic activity of 2 is investigated for the Heck reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 1709-1711 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 44 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 4 2005 |
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Keywords
- Heck reaction
- Homogeneous catalysis
- Palladium
- Pincer complexes
- Reduction
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Redox-induced collapse and regeneration of a pincer-type complex framework : A nonplanar coordination mode of palladium(II). / Frech, Christian M.; Shimon, Linda J W; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 44, No. 11, 04.03.2005, p. 1709-1711.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Redox-induced collapse and regeneration of a pincer-type complex framework
T2 - A nonplanar coordination mode of palladium(II)
AU - Frech, Christian M.
AU - Shimon, Linda J W
AU - Milstein, David
PY - 2005/3/4
Y1 - 2005/3/4
N2 - (Chemical Equation Presented) Unequal partners: One-electron reduction of a pincer-type palladium complex 1 results in collapse of the pincer system and formation of a novel bimetallic diamagnetic complex containing a linearly coordinated 14 e Pd0 center and a non-planar PdII unit (2). The reaction is reversed by oxidation with Ag+ or organic halides. The catalytic activity of 2 is investigated for the Heck reaction.
AB - (Chemical Equation Presented) Unequal partners: One-electron reduction of a pincer-type palladium complex 1 results in collapse of the pincer system and formation of a novel bimetallic diamagnetic complex containing a linearly coordinated 14 e Pd0 center and a non-planar PdII unit (2). The reaction is reversed by oxidation with Ag+ or organic halides. The catalytic activity of 2 is investigated for the Heck reaction.
KW - Heck reaction
KW - Homogeneous catalysis
KW - Palladium
KW - Pincer complexes
KW - Reduction
UR - http://www.scopus.com/inward/record.url?scp=17144397739&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=17144397739&partnerID=8YFLogxK
U2 - 10.1002/anie.200462386
DO - 10.1002/anie.200462386
M3 - Article
VL - 44
SP - 1709
EP - 1711
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 11
ER -