Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation

Prosenjit Daw, Amit Kumar, Dror Oren, Noel Angel Espinosa-Jalapa, Dipankar Srimani, Yael Diskin-Posner, Gregory Leitus, Linda J.W. Shimon, Raanan Carmieli, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C-C bond at the C9 position of the acridine ring.

Original languageEnglish
Pages (from-to)279-285
Number of pages7
JournalOrganometallics
Volume39
Issue number2
DOIs
Publication statusPublished - Jan 27 2020

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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    Daw, P., Kumar, A., Oren, D., Espinosa-Jalapa, N. A., Srimani, D., Diskin-Posner, Y., Leitus, G., Shimon, L. J. W., Carmieli, R., Ben-David, Y., & Milstein, D. (2020). Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation. Organometallics, 39(2), 279-285. https://doi.org/10.1021/acs.organomet.9b00607