Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation

Prosenjit Daw; Amit Kumar; Dror Oren; Noel Angel Espinosa-Jalapa; Dipankar Srimani; Yael Diskin-Posner; Gregory Leitus; Linda J.W. Shimon; Raanan Carmieli; Yehoshoa Ben-David; David Milstein

doi:10.1021/acs.organomet.9b00607

Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation

Prosenjit Daw, Amit Kumar, Dror Oren, Noel Angel Espinosa-Jalapa, Dipankar Srimani, Yael Diskin-Posner, Gregory Leitus, Linda J.W. Shimon, Raanan Carmieli, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C-C bond at the C9 position of the acridine ring.

Original language	English
Pages (from-to)	279-285
Number of pages	7
Journal	Organometallics
Volume	39
Issue number	2
DOIs	https://doi.org/10.1021/acs.organomet.9b00607
Publication status	Published - Jan 27 2020

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Daw, P., Kumar, A., Oren, D., Espinosa-Jalapa, N. A., Srimani, D., Diskin-Posner, Y., Leitus, G., Shimon, L. J. W., Carmieli, R., Ben-David, Y., & Milstein, D. (2020). Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation. Organometallics, 39(2), 279-285. https://doi.org/10.1021/acs.organomet.9b00607

Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation. / Daw, Prosenjit; Kumar, Amit; Oren, Dror; Espinosa-Jalapa, Noel Angel; Srimani, Dipankar; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J.W.; Carmieli, Raanan; Ben-David, Yehoshoa; Milstein, David.

In: Organometallics, Vol. 39, No. 2, 27.01.2020, p. 279-285.

Research output: Contribution to journal › Article

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AB - Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C-C bond at the C9 position of the acridine ring.

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10.1021/acs.organomet.9b00607