Regeneration of Au/γ-Al2O3 deactivated by CO oxidation

H. S. Oh, C. K. Costello, C. Cheung, H. H. Kung, M. C. Kung

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40 Citations (Scopus)

Abstract

Au/γ-Al2O3 deactivates in CO oxidation, but it exhibits stable activity in selective CO oxidation (SCO) in the presence of H2. The activity for CO oxidation could be suppressed significantly by thermal treatment at 100°C, and the lost activity could be recovered by exposing the catalyst to water vapor at room temperature. A catalyst deactivated in CO oxidation could be regenerated by exposing it to H2 at room temperature or by running the SCO reaction over it. The results can be explained with a reaction mechanism for CO oxidation involving an active site that consists of an ensemble of metallic Au atoms and Au-hydroxyl. Deactivation in CO oxidation is due to the formation of an inactive carbonate, and deactivation by thermal treatment is due to dehydroxylation of the Au-hydroxyl.

Original languageEnglish
Pages (from-to)375-381
Number of pages7
JournalStudies in Surface Science and Catalysis
Volume139
Publication statusPublished - Jan 1 2001

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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    Oh, H. S., Costello, C. K., Cheung, C., Kung, H. H., & Kung, M. C. (2001). Regeneration of Au/γ-Al2O3 deactivated by CO oxidation. Studies in Surface Science and Catalysis, 139, 375-381.