Abstract
The relative rate technique has been used to measure rate constants for the reaction of chlorine atoms with nitro methane, nitro ethane, nitro propane, nitro butane, nitro pentane, ethyl nitrate, isopropyl nitrate, n-propyl nitrate, 2-pentyl nitrate, and 2-heptyl nitrate. Decay rates of these organic species were measured relative to one or more of the following reference compounds; n-butane, ethane, chloroethane, and methane. Experiments were performed at 295 ± 2 K and atmospheric pressure (approximately 740 torr) of synthetic air. The results are discussed with respect to the previous literature data and to the modelling of these compounds in the atmosphere.
| Original language | English |
|---|---|
| Pages (from-to) | 665-671 |
| Number of pages | 7 |
| Journal | International Journal of Chemical Kinetics |
| Volume | 22 |
| Issue number | 7 |
| Publication status | Published - Jul 1990 |
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ASJC Scopus subject areas
- Medicine(all)
- Catalysis
- Engineering(all)
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Relative rate study of the reaction of Cl atoms with a series of alkyl nitrates and nitro alkanes in air at 295 ± 2 K. / Wallington, T. J.; Hinman, M. M.; Andino, Jean M.; Siegl, W. O.; Japar, S. M.
In: International Journal of Chemical Kinetics, Vol. 22, No. 7, 07.1990, p. 665-671.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Relative rate study of the reaction of Cl atoms with a series of alkyl nitrates and nitro alkanes in air at 295 ± 2 K
AU - Wallington, T. J.
AU - Hinman, M. M.
AU - Andino, Jean M.
AU - Siegl, W. O.
AU - Japar, S. M.
PY - 1990/7
Y1 - 1990/7
N2 - The relative rate technique has been used to measure rate constants for the reaction of chlorine atoms with nitro methane, nitro ethane, nitro propane, nitro butane, nitro pentane, ethyl nitrate, isopropyl nitrate, n-propyl nitrate, 2-pentyl nitrate, and 2-heptyl nitrate. Decay rates of these organic species were measured relative to one or more of the following reference compounds; n-butane, ethane, chloroethane, and methane. Experiments were performed at 295 ± 2 K and atmospheric pressure (approximately 740 torr) of synthetic air. The results are discussed with respect to the previous literature data and to the modelling of these compounds in the atmosphere.
AB - The relative rate technique has been used to measure rate constants for the reaction of chlorine atoms with nitro methane, nitro ethane, nitro propane, nitro butane, nitro pentane, ethyl nitrate, isopropyl nitrate, n-propyl nitrate, 2-pentyl nitrate, and 2-heptyl nitrate. Decay rates of these organic species were measured relative to one or more of the following reference compounds; n-butane, ethane, chloroethane, and methane. Experiments were performed at 295 ± 2 K and atmospheric pressure (approximately 740 torr) of synthetic air. The results are discussed with respect to the previous literature data and to the modelling of these compounds in the atmosphere.
UR - http://www.scopus.com/inward/record.url?scp=0025464597&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0025464597&partnerID=8YFLogxK
M3 - Article
VL - 22
SP - 665
EP - 671
JO - International Journal of Chemical Kinetics
JF - International Journal of Chemical Kinetics
SN - 0538-8066
IS - 7
ER -