Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr): A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution

Xue Zhong Sun; David C. Grills; Sergei M. Nikiforov; Martyn Poliakoff; Michael W. George

doi:10.1021/ja962939j

Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr): A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution

Xue Zhong Sun, David C. Grills, Sergei M. Nikiforov, Martyn Poliakoff, Michael W. George

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

Employing fast time-resolved infrared (TRIR) spectroscopy we have characterized CpRe(CO)₂(n-heptane), CpRe(CO)₂(Xe), and CpRe(CO)₂(Kr) (Cp = η⁵-C₅H₅) at or above room temperature in n-heptane, supercritical Xe, and Kr solution. The reactivity of CpRe(CO)₂(n-heptane) with CO (k₂ = 2.1 (±0.5) x 10³ mol^-1 dm³ s^-1) shows this complex to be the least reactive of the reported organometallic alkane complexes. We report a trend in reactivity of the early transition metal alkane complexes. CpRe(CO)₂(Xe) and CpRe(CO)₂(Kr) are also shown to have significant stability. CpRe(CO)₂(Xe) is less reactive toward CO than all of the reported alkane complexes except CpRe(CO)₂(n-heptane).

Original language	English
Pages (from-to)	7521-7525
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	119
Issue number	32
DOIs	https://doi.org/10.1021/ja962939j
Publication status	Published - Aug 13 1997

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1021/ja962939j

Fingerprint Dive into the research topics of 'Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr): A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution'. Together they form a unique fingerprint.

Cite this

Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr) : A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution. / Sun, Xue Zhong; Grills, David C.; Nikiforov, Sergei M.; Poliakoff, Martyn; George, Michael W.

In: Journal of the American Chemical Society, Vol. 119, No. 32, 13.08.1997, p. 7521-7525.

Research output: Contribution to journal › Article › peer-review

Sun, Xue Zhong ; Grills, David C. ; Nikiforov, Sergei M. ; Poliakoff, Martyn ; George, Michael W. / Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr) : A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution. In: Journal of the American Chemical Society. 1997 ; Vol. 119, No. 32. pp. 7521-7525.

@article{61e7c4913fea48eda0079dfb1ff8725d,

title = "Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr): A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution",

abstract = "Employing fast time-resolved infrared (TRIR) spectroscopy we have characterized CpRe(CO)2(n-heptane), CpRe(CO)2(Xe), and CpRe(CO)2(Kr) (Cp = η5-C5H5) at or above room temperature in n-heptane, supercritical Xe, and Kr solution. The reactivity of CpRe(CO)2(n-heptane) with CO (k2 = 2.1 (±0.5) x 103 mol-1 dm3 s-1) shows this complex to be the least reactive of the reported organometallic alkane complexes. We report a trend in reactivity of the early transition metal alkane complexes. CpRe(CO)2(Xe) and CpRe(CO)2(Kr) are also shown to have significant stability. CpRe(CO)2(Xe) is less reactive toward CO than all of the reported alkane complexes except CpRe(CO)2(n-heptane).",

author = "Sun, {Xue Zhong} and Grills, {David C.} and Nikiforov, {Sergei M.} and Martyn Poliakoff and George, {Michael W.}",

year = "1997",

month = aug,

day = "13",

doi = "10.1021/ja962939j",

language = "English",

volume = "119",

pages = "7521--7525",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "32",

}

TY - JOUR

T1 - Remarkable stability of (η5-C5H5)Re(CO)2L (L = n-heptane, xe, and kr)

T2 - A time-resolved infrared spectroscopic study of (η5-C5H5)Re(CO)3 in conventional and supercritical fluid solution

AU - Sun, Xue Zhong

AU - Grills, David C.

AU - Nikiforov, Sergei M.

AU - Poliakoff, Martyn

AU - George, Michael W.

PY - 1997/8/13

Y1 - 1997/8/13

N2 - Employing fast time-resolved infrared (TRIR) spectroscopy we have characterized CpRe(CO)2(n-heptane), CpRe(CO)2(Xe), and CpRe(CO)2(Kr) (Cp = η5-C5H5) at or above room temperature in n-heptane, supercritical Xe, and Kr solution. The reactivity of CpRe(CO)2(n-heptane) with CO (k2 = 2.1 (±0.5) x 103 mol-1 dm3 s-1) shows this complex to be the least reactive of the reported organometallic alkane complexes. We report a trend in reactivity of the early transition metal alkane complexes. CpRe(CO)2(Xe) and CpRe(CO)2(Kr) are also shown to have significant stability. CpRe(CO)2(Xe) is less reactive toward CO than all of the reported alkane complexes except CpRe(CO)2(n-heptane).

AB - Employing fast time-resolved infrared (TRIR) spectroscopy we have characterized CpRe(CO)2(n-heptane), CpRe(CO)2(Xe), and CpRe(CO)2(Kr) (Cp = η5-C5H5) at or above room temperature in n-heptane, supercritical Xe, and Kr solution. The reactivity of CpRe(CO)2(n-heptane) with CO (k2 = 2.1 (±0.5) x 103 mol-1 dm3 s-1) shows this complex to be the least reactive of the reported organometallic alkane complexes. We report a trend in reactivity of the early transition metal alkane complexes. CpRe(CO)2(Xe) and CpRe(CO)2(Kr) are also shown to have significant stability. CpRe(CO)2(Xe) is less reactive toward CO than all of the reported alkane complexes except CpRe(CO)2(n-heptane).

UR - http://www.scopus.com/inward/record.url?scp=0030810664&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030810664&partnerID=8YFLogxK

U2 - 10.1021/ja962939j

DO - 10.1021/ja962939j

M3 - Article

AN - SCOPUS:0030810664

VL - 119

SP - 7521

EP - 7525

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 32

ER -