Reusable homogeneous catalytic system for hydrogen production from methanol and water

Peng Hu; Yael Diskin-Posner; Yehoshoa Ben-David; David Milstein

doi:10.1021/cs500937f

Reusable homogeneous catalytic system for hydrogen production from methanol and water

Peng Hu, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

102 Citations (Scopus)

Abstract

An efficient system catalyzed by a Ru-PNN pincer complex was developed for reforming methanol to H₂ and CO₂ (absorbed by base) under relatively low temperature (around 100 °C), and good yields of H₂ were obtained (∼80%). The catalyst solution can be reused without isolation and purification, with no decrease in catalytic activity being observed for a period of ∼1 month. Decomposition of formic acid, which is likely to be the last step of the methanol reforming reaction, was also investigated, and the formic acid adduct of the catalyst was fully characterized spectroscopically and by X-ray crystallography.

Original language	English
Pages (from-to)	2649-2652
Number of pages	4
Journal	ACS Catalysis
Volume	4
Issue number	8
DOIs	https://doi.org/10.1021/cs500937f
Publication status	Published - Jan 1 2014

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Keywords

dehydrogenation
hydrogen storage
methanol reforming
reusable catalyst
ruthenium pincer complex

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Hu, P., Diskin-Posner, Y., Ben-David, Y., & Milstein, D. (2014). Reusable homogeneous catalytic system for hydrogen production from methanol and water. ACS Catalysis, 4(8), 2649-2652. https://doi.org/10.1021/cs500937f

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10.1021/cs500937f