Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic

Stuart E. Smith; Jenny Y. Yang; Daniel L. Dubois; R. Morris Bullock

doi:10.1002/anie.201108461

Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic

Stuart E. Smith, Jenny Y. Yang, Daniel L. Dubois, R. Morris Bullock

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

99 Citations (Scopus)

Abstract

An efficient ligand combination: A new bis(diphosphine) nickel(II) complex (see picture) is described. A ΔG° value of 0.84 kcal mol ^-1 for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displayed reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, which are characteristic for hydrogenase enzymes.

Original language	English
Pages (from-to)	3152-3155
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	13
DOIs	https://doi.org/10.1002/anie.201108461
Publication status	Published - Mar 26 2012

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Keywords

catalysis
electrochemistry
homogeneous catalysis
hydrogen
hydrogenase enzymes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Smith, S. E., Yang, J. Y., Dubois, D. L., & Bullock, R. M. (2012). Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic. Angewandte Chemie - International Edition, 51(13), 3152-3155. https://doi.org/10.1002/anie.201108461

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10.1002/anie.201108461