Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic

Stuart E. Smith, Jenny Y. Yang, Daniel L. Dubois, R. Morris Bullock

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99 Citations (Scopus)

Abstract

An efficient ligand combination: A new bis(diphosphine) nickel(II) complex (see picture) is described. A ΔG° value of 0.84 kcal mol -1 for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displayed reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, which are characteristic for hydrogenase enzymes.

Original languageEnglish
Pages (from-to)3152-3155
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number13
DOIs
Publication statusPublished - Mar 26 2012

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Keywords

  • catalysis
  • electrochemistry
  • homogeneous catalysis
  • hydrogen
  • hydrogenase enzymes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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