Revisiting Conversion Reaction Mechanisms in Lithium Batteries: Lithiation-Driven Topotactic Transformation in FeF 2

Khim Karki, Lijun Wu, Ying Ma, Mark J. Armstrong, Justin D. Holmes, Stephen H. Garofalini, Yimei Zhu, Eric A. Stach, Feng Wang

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Intercalation-type electrodes have now been commonly employed in today's batteries as such materials are capable of storing and releasing lithium reversibly via topotactic transformation, conducive to small structural change, but they have limited interstitial sites to hold Li. In contrast, conversion electrodes feature high Li-storage capacity, but often undergo large structural change during (de)lithiation, resulting in cycling instability. One exception is iron fluoride (FeF 2 ), a conversion-type cathode that exhibits both high capacity and high cycling stability. Herein, we report a lithiation-driven topotactic transformation in a single crystal of FeF 2 , unveiled by in situ visualization of the spatial and crystallographic correlation between the parent and converted phases. Specifically, conversion in FeF 2 resembles the intercalation process but involves transport of both Li + and Fe 2+ ions within the F-anion array, leading to formation of Fe preferentially along specific crystallographic orientations of FeF 2 . Throughout the process, the F-anion framework is retained, creating a checkerboard-like structure, within which the volume change is largely compensated, thereby enabling the high cyclability in FeF 2 . Findings from this study, with unique insights into conversion reaction mechanisms, may help to pave the way for designing conversion-type electrodes for the next-generation high energy lithium batteries.

Original languageEnglish
Pages (from-to)17915-17922
Number of pages8
JournalJournal of the American Chemical Society
Volume140
Issue number51
DOIs
Publication statusPublished - Dec 26 2018

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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