TY - JOUR
T1 - Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) 5, and structure of a novel Mn2(CO)9(η 1-aldehyde) complex
AU - Bullock, R. Morris
AU - Rappoli, Brian J.
AU - Samsel, Edward G.
AU - Rheingold, Arnold L.
PY - 1989/1/1
Y1 - 1989/1/1
N2 - An η1-aldehyde complex, Mn2(CO) 9[Me(Ph)C=CHCH2CH2CHO], was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η1 (σ) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO) 9.
AB - An η1-aldehyde complex, Mn2(CO) 9[Me(Ph)C=CHCH2CH2CHO], was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η1 (σ) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO) 9.
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U2 - 10.1039/C39890000261
DO - 10.1039/C39890000261
M3 - Article
SP - 261
EP - 263
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 4
ER -