Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) 5, and structure of a novel Mn2(CO)9(η 1-aldehyde) complex

R. Morris Bullock; Brian J. Rappoli; Edward G. Samsel; Arnold L. Rheingold

doi:10.1039/C39890000261

Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) ₅, and structure of a novel Mn₂(CO)₉(η ¹-aldehyde) complex

R. Morris Bullock, Brian J. Rappoli, Edward G. Samsel, Arnold L. Rheingold

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

Abstract

An η¹-aldehyde complex, Mn₂(CO) ₉[Me(Ph)C=CHCH₂CH₂CHO], was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)₅; the crystal structure of this unusual compound confirmed the η¹ (σ) bonding of the aldehyde oxygen as an equatorial ligand on Mn₂(CO) ₉.

Original language	English
Pages (from-to)	261-263
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39890000261
Publication status	Published - Jan 1 1989

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Molecular Medicine

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Bullock, R. M., Rappoli, B. J., Samsel, E. G., & Rheingold, A. L. (1989). Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) ₅, and structure of a novel Mn₂(CO)₉(η ¹-aldehyde) complex. Journal of the Chemical Society, Chemical Communications, (4), 261-263. https://doi.org/10.1039/C39890000261

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abstract = "An η1-aldehyde complex, Mn2(CO) 9[Me(Ph)C=CHCH2CH2CHO], was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η1 (σ) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO) 9.",

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10.1039/C39890000261