Abstract
An η1-aldehyde complex, Mn2(CO) 9[Me(Ph)C=CHCH2CH2CHO], was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η1 (σ) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO) 9.
| Original language | English |
|---|---|
| Pages (from-to) | 261-263 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Jan 1 1989 |
ASJC Scopus subject areas
- Molecular Medicine
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Bullock, R. M., Rappoli, B. J., Samsel, E. G., & Rheingold, A. L. (1989). Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) 5, and structure of a novel Mn2(CO)9(η 1-aldehyde) complex. Journal of the Chemical Society, Chemical Communications, (4), 261-263. https://doi.org/10.1039/C39890000261