Role of metal electronic properties in tuning the second-order nonlinear optical response of coordination complexes. A combined experimental and theoretical investigation of a homologous series of (N,N′-disalicylidene-1,2-phenylenediaminato)M(II) (M = Co, Ni, Cu) complexes

Santo Di Bella, Ignazio Fragalà, Isabelle Ledoux, Tobin J Marks

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Abstract

The role of metal electronic configuration in determining the second-order nonlinear optical response of the homologous series of planar, thermally robust M(salophen) (M = Co, Ni, Cu) transition metal complexes is investigated by electric field induced second harmonic generation experiments and ZINDO quantum chemical calculations. Both the experimental data and those derived from the theoretical calculations (which are in good agreement) indicate that, on passing from closed-shell d8 Ni(II) to the open-shell d9 Cu(II) and d7 Co(II) analogues, hyperpolarizability values increase by a factor of ∼3 and ∼8, respectively. These indicate a major role of metal electronic configuration in determining the second-order nonlinear optical response. Partially resonant solution-phase hyperpolarizability values as high as (-170 ± 40) × 10-30 cm5 esu-1 (ℏω = 0.92 eV; μ·β = 1340 × 10-48 esu ≈ 2 × that for 4-(N,N-dimethylamino)-4′-nitrostilbene) are observed for the Co(salophen) complex. The greater second-order responses of the Cu(II) and Co(II) complexes can be understood in terms of the different natures of the contributing electronic excited states. In particular, the large nonlinearities of Cu(salophen) and Co(salophen) are due to more intense low-energy charge-transfer transitions and the existence of either higher (M = Cu) or lower (M = Co) lying metal-to-ligand charge-transfer states. While, for the closed-shell Ni(salophen) complex, the two-state model represents a suitable approximation for describing the nonlinearity, it breaks down in the case of Cu(salophen) and Co(salophen), since other states contribute to the response. Experimental linear and nonlinear optical features are fully consistent with the theoretical calculations.

Original languageEnglish
Pages (from-to)9481-9485
Number of pages5
JournalJournal of the American Chemical Society
Volume117
Issue number37
Publication statusPublished - Sep 20 1995

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Coordination Complexes
Electronic properties
Tuning
Metals
Charge transfer
Harmonic generation
Metal complexes
Excited states
Transition metals
Ligands
Electric fields
Energy Transfer
salophen
Experiments

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{8c95dac1a9a14f498fd18b08f95bb969,
title = "Role of metal electronic properties in tuning the second-order nonlinear optical response of coordination complexes. A combined experimental and theoretical investigation of a homologous series of (N,N′-disalicylidene-1,2-phenylenediaminato)M(II) (M = Co, Ni, Cu) complexes",
abstract = "The role of metal electronic configuration in determining the second-order nonlinear optical response of the homologous series of planar, thermally robust M(salophen) (M = Co, Ni, Cu) transition metal complexes is investigated by electric field induced second harmonic generation experiments and ZINDO quantum chemical calculations. Both the experimental data and those derived from the theoretical calculations (which are in good agreement) indicate that, on passing from closed-shell d8 Ni(II) to the open-shell d9 Cu(II) and d7 Co(II) analogues, hyperpolarizability values increase by a factor of ∼3 and ∼8, respectively. These indicate a major role of metal electronic configuration in determining the second-order nonlinear optical response. Partially resonant solution-phase hyperpolarizability values as high as (-170 ± 40) × 10-30 cm5 esu-1 (ℏω = 0.92 eV; μ·β = 1340 × 10-48 esu ≈ 2 × that for 4-(N,N-dimethylamino)-4′-nitrostilbene) are observed for the Co(salophen) complex. The greater second-order responses of the Cu(II) and Co(II) complexes can be understood in terms of the different natures of the contributing electronic excited states. In particular, the large nonlinearities of Cu(salophen) and Co(salophen) are due to more intense low-energy charge-transfer transitions and the existence of either higher (M = Cu) or lower (M = Co) lying metal-to-ligand charge-transfer states. While, for the closed-shell Ni(salophen) complex, the two-state model represents a suitable approximation for describing the nonlinearity, it breaks down in the case of Cu(salophen) and Co(salophen), since other states contribute to the response. Experimental linear and nonlinear optical features are fully consistent with the theoretical calculations.",
author = "{Di Bella}, Santo and Ignazio Fragal{\`a} and Isabelle Ledoux and Marks, {Tobin J}",
year = "1995",
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T1 - Role of metal electronic properties in tuning the second-order nonlinear optical response of coordination complexes. A combined experimental and theoretical investigation of a homologous series of (N,N′-disalicylidene-1,2-phenylenediaminato)M(II) (M = Co, Ni, Cu) complexes

AU - Di Bella, Santo

AU - Fragalà, Ignazio

AU - Ledoux, Isabelle

AU - Marks, Tobin J

PY - 1995/9/20

Y1 - 1995/9/20

N2 - The role of metal electronic configuration in determining the second-order nonlinear optical response of the homologous series of planar, thermally robust M(salophen) (M = Co, Ni, Cu) transition metal complexes is investigated by electric field induced second harmonic generation experiments and ZINDO quantum chemical calculations. Both the experimental data and those derived from the theoretical calculations (which are in good agreement) indicate that, on passing from closed-shell d8 Ni(II) to the open-shell d9 Cu(II) and d7 Co(II) analogues, hyperpolarizability values increase by a factor of ∼3 and ∼8, respectively. These indicate a major role of metal electronic configuration in determining the second-order nonlinear optical response. Partially resonant solution-phase hyperpolarizability values as high as (-170 ± 40) × 10-30 cm5 esu-1 (ℏω = 0.92 eV; μ·β = 1340 × 10-48 esu ≈ 2 × that for 4-(N,N-dimethylamino)-4′-nitrostilbene) are observed for the Co(salophen) complex. The greater second-order responses of the Cu(II) and Co(II) complexes can be understood in terms of the different natures of the contributing electronic excited states. In particular, the large nonlinearities of Cu(salophen) and Co(salophen) are due to more intense low-energy charge-transfer transitions and the existence of either higher (M = Cu) or lower (M = Co) lying metal-to-ligand charge-transfer states. While, for the closed-shell Ni(salophen) complex, the two-state model represents a suitable approximation for describing the nonlinearity, it breaks down in the case of Cu(salophen) and Co(salophen), since other states contribute to the response. Experimental linear and nonlinear optical features are fully consistent with the theoretical calculations.

AB - The role of metal electronic configuration in determining the second-order nonlinear optical response of the homologous series of planar, thermally robust M(salophen) (M = Co, Ni, Cu) transition metal complexes is investigated by electric field induced second harmonic generation experiments and ZINDO quantum chemical calculations. Both the experimental data and those derived from the theoretical calculations (which are in good agreement) indicate that, on passing from closed-shell d8 Ni(II) to the open-shell d9 Cu(II) and d7 Co(II) analogues, hyperpolarizability values increase by a factor of ∼3 and ∼8, respectively. These indicate a major role of metal electronic configuration in determining the second-order nonlinear optical response. Partially resonant solution-phase hyperpolarizability values as high as (-170 ± 40) × 10-30 cm5 esu-1 (ℏω = 0.92 eV; μ·β = 1340 × 10-48 esu ≈ 2 × that for 4-(N,N-dimethylamino)-4′-nitrostilbene) are observed for the Co(salophen) complex. The greater second-order responses of the Cu(II) and Co(II) complexes can be understood in terms of the different natures of the contributing electronic excited states. In particular, the large nonlinearities of Cu(salophen) and Co(salophen) are due to more intense low-energy charge-transfer transitions and the existence of either higher (M = Cu) or lower (M = Co) lying metal-to-ligand charge-transfer states. While, for the closed-shell Ni(salophen) complex, the two-state model represents a suitable approximation for describing the nonlinearity, it breaks down in the case of Cu(salophen) and Co(salophen), since other states contribute to the response. Experimental linear and nonlinear optical features are fully consistent with the theoretical calculations.

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