Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions

Dipankar Srimani; Ekambaram Balaraman; Boopathy Gnanaprakasam; Yehoshoa Ben-David; David Milstein

doi:10.1002/adsc.201200438

Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions

Dipankar Srimani, Ekambaram Balaraman, Boopathy Gnanaprakasam, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

79 Citations (Scopus)

Abstract

Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.

Original language	English
Pages (from-to)	2403-2406
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	354
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201200438
Publication status	Published - Sep 17 2012

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Keywords

cross-esterification
dehydrogenation
homogeneous catalysis
oxidative coupling
ruthenium pincer complexes

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Cite this

Srimani, D., Balaraman, E., Gnanaprakasam, B., Ben-David, Y., & Milstein, D. (2012). Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions. Advanced Synthesis and Catalysis, 354(13), 2403-2406. https://doi.org/10.1002/adsc.201200438

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AU - Milstein, David

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10.1002/adsc.201200438