Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions

Dipankar Srimani; Ekambaram Balaraman; Boopathy Gnanaprakasam; Yehoshoa Ben-David; David Milstein

doi:10.1002/adsc.201200438

Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions

Dipankar Srimani, Ekambaram Balaraman, Boopathy Gnanaprakasam, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.

Original language	English
Pages (from-to)	2403-2406
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	354
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201200438
Publication status	Published - Sep 17 2012

Keywords

cross-esterification
dehydrogenation
homogeneous catalysis
oxidative coupling
ruthenium pincer complexes

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/adsc.201200438

Fingerprint Dive into the research topics of 'Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions'. Together they form a unique fingerprint.

Cite this

Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions. / Srimani, Dipankar; Balaraman, Ekambaram; Gnanaprakasam, Boopathy; Ben-David, Yehoshoa; Milstein, David.

In: Advanced Synthesis and Catalysis, Vol. 354, No. 13, 17.09.2012, p. 2403-2406.

Research output: Contribution to journal › Article › peer-review

@article{d87aeeb6ba374ef4b6a8ce835c3b8516,

title = "Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions",

abstract = "Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.",

keywords = "cross-esterification, dehydrogenation, homogeneous catalysis, oxidative coupling, ruthenium pincer complexes",

author = "Dipankar Srimani and Ekambaram Balaraman and Boopathy Gnanaprakasam and Yehoshoa Ben-David and David Milstein",

year = "2012",

month = sep,

day = "17",

doi = "10.1002/adsc.201200438",

language = "English",

volume = "354",

pages = "2403--2406",

journal = "Journal fur Praktische Chemie",

issn = "1436-9966",

publisher = "Wiley-VCH Verlag",

number = "13",

}

TY - JOUR

T1 - Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions

AU - Srimani, Dipankar

AU - Balaraman, Ekambaram

AU - Gnanaprakasam, Boopathy

AU - Ben-David, Yehoshoa

AU - Milstein, David

PY - 2012/9/17

Y1 - 2012/9/17

N2 - Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.

AB - Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.

KW - cross-esterification

KW - dehydrogenation

KW - homogeneous catalysis

KW - oxidative coupling

KW - ruthenium pincer complexes

UR - http://www.scopus.com/inward/record.url?scp=84865795296&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84865795296&partnerID=8YFLogxK

U2 - 10.1002/adsc.201200438

DO - 10.1002/adsc.201200438

M3 - Article

AN - SCOPUS:84865795296

VL - 354

SP - 2403

EP - 2406

JO - Journal fur Praktische Chemie

JF - Journal fur Praktische Chemie

SN - 1436-9966

IS - 13

ER -