Abstract
Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 2403-2406 |
| Number of pages | 4 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 354 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Sep 17 2012 |
Keywords
- cross-esterification
- dehydrogenation
- homogeneous catalysis
- oxidative coupling
- ruthenium pincer complexes
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Srimani, D., Balaraman, E., Gnanaprakasam, B., Ben-David, Y., & Milstein, D. (2012). Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions. Advanced Synthesis and Catalysis, 354(13), 2403-2406. https://doi.org/10.1002/adsc.201200438