Abstract
Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 2403-2406 |
| Number of pages | 4 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 354 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Sep 17 2012 |
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Keywords
- cross-esterification
- dehydrogenation
- homogeneous catalysis
- oxidative coupling
- ruthenium pincer complexes
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
Cite this
Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions. / Srimani, Dipankar; Balaraman, Ekambaram; Gnanaprakasam, Boopathy; Ben-David, Yehoshoa; Milstein, David.
In: Advanced Synthesis and Catalysis, Vol. 354, No. 13, 17.09.2012, p. 2403-2406.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Ruthenium pincer-catalyzed cross-dehydrogenative coupling of primary alcohols with secondary alcohols under neutral conditions
AU - Srimani, Dipankar
AU - Balaraman, Ekambaram
AU - Gnanaprakasam, Boopathy
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2012/9/17
Y1 - 2012/9/17
N2 - Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.
AB - Cross-dehydrogenative coupling of primary alcohols with secondary alcohols to obtain mixed esters with the liberation of molecular hydrogen is achieved in high yield and good selectivity under neutral conditions, using a bipyridyl-based PNN ruthenium(II) pincer catalyst.
KW - cross-esterification
KW - dehydrogenation
KW - homogeneous catalysis
KW - oxidative coupling
KW - ruthenium pincer complexes
UR - http://www.scopus.com/inward/record.url?scp=84865795296&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84865795296&partnerID=8YFLogxK
U2 - 10.1002/adsc.201200438
DO - 10.1002/adsc.201200438
M3 - Article
VL - 354
SP - 2403
EP - 2406
JO - Journal fur Praktische Chemie
JF - Journal fur Praktische Chemie
SN - 1436-9966
IS - 13
ER -