SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Yan Xu; Nicolaas A. Vermeulen; Yangyang Liu; Joseph T. Hupp; Omar K. Farha

doi:10.1002/ejic.201600069

SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Yan Xu, Nicolaas A. Vermeulen, Yangyang Liu, Joseph T. Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit – the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node – of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.

Original language	English
Pages (from-to)	4345-4348
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	27
DOIs	https://doi.org/10.1002/ejic.201600069
Publication status	Published - Sep 2016

Keywords

Carboxylate ligands
Coordination modes
Metal-organic frameworks
Synthesis design
Transmetalation

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.201600069

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SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework. / Xu, Yan; Vermeulen, Nicolaas A.; Liu, Yangyang; Hupp, Joseph T.; Farha, Omar K.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 27, 09.2016, p. 4345-4348.

Research output: Contribution to journal › Article › peer-review

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abstract = "A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit – the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node – of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.",

keywords = "Carboxylate ligands, Coordination modes, Metal-organic frameworks, Synthesis design, Transmetalation",

author = "Yan Xu and Vermeulen, {Nicolaas A.} and Yangyang Liu and Hupp, {Joseph T.} and Farha, {Omar K.}",

note = "Funding Information: The authors thank Yongchul G. Chung for his contribution of preparing a simulated structure of non-interpenetrated Zn2(ndc)2(bpy). J. T. H. thanks David J. Hupp for introducing him to the Theseus' Paradox. We gratefully acknowledge funding from the U. S. Dept. of Energy, Office of Science, Basic Energy Sciences Program through grant DE-FG02-08ER15967. Y. X. acknowledges the financial support from the program of China Scholarship Council (grant number 201406085036).",

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