Abstract
A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.
| Original language | English |
|---|---|
| Journal | European Journal of Inorganic Chemistry |
| DOIs | |
| Publication status | Accepted/In press - 2016 |
Keywords
- Carboxylate ligands
- Coordination modes
- Metal-organic frameworks
- Synthesis design
- Transmetalation
ASJC Scopus subject areas
- Inorganic Chemistry
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Xu, Y., Vermeulen, N. A., Liu, Y., Hupp, J. T., & Farha, O. K. (Accepted/In press). SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.201600069