Abstract
A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.
| Original language | English |
|---|---|
| Journal | European Journal of Inorganic Chemistry |
| DOIs | |
| Publication status | Accepted/In press - 2016 |
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Keywords
- Carboxylate ligands
- Coordination modes
- Metal-organic frameworks
- Synthesis design
- Transmetalation
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework. / Xu, Yan; Vermeulen, Nicolaas A.; Liu, Yangyang; Hupp, Joseph T; Farha, Omar K.
In: European Journal of Inorganic Chemistry, 2016.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework
AU - Xu, Yan
AU - Vermeulen, Nicolaas A.
AU - Liu, Yangyang
AU - Hupp, Joseph T
AU - Farha, Omar K.
PY - 2016
Y1 - 2016
N2 - A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.
AB - A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.
KW - Carboxylate ligands
KW - Coordination modes
KW - Metal-organic frameworks
KW - Synthesis design
KW - Transmetalation
UR - http://www.scopus.com/inward/record.url?scp=84961263068&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84961263068&partnerID=8YFLogxK
U2 - 10.1002/ejic.201600069
DO - 10.1002/ejic.201600069
M3 - Article
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
ER -