Abstract
A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit – the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node – of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.
Original language | English |
---|---|
Pages (from-to) | 4345-4348 |
Number of pages | 4 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2016 |
Issue number | 27 |
DOIs | |
Publication status | Published - Sep 2016 |
Keywords
- Carboxylate ligands
- Coordination modes
- Metal-organic frameworks
- Synthesis design
- Transmetalation
ASJC Scopus subject areas
- Inorganic Chemistry