SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Yan Xu; Nicolaas A. Vermeulen; Yangyang Liu; Joseph T Hupp; Omar K. Farha

doi:10.1002/ejic.201600069

SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Yan Xu, Nicolaas A. Vermeulen, Yangyang Liu, Joseph T Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.

Original language	English
Journal	European Journal of Inorganic Chemistry
DOIs	https://doi.org/10.1002/ejic.201600069
Publication status	Accepted/In press - 2016

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Keywords

Carboxylate ligands
Coordination modes
Metal-organic frameworks
Synthesis design
Transmetalation

ASJC Scopus subject areas

Inorganic Chemistry

Cite this

Xu, Y., Vermeulen, N. A., Liu, Y., Hupp, J. T., & Farha, O. K. (Accepted/In press). SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.201600069

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Access to Document

10.1002/ejic.201600069