SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

Yan Xu, Nicolaas A. Vermeulen, Yangyang Liu, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.

Original languageEnglish
JournalEuropean Journal of Inorganic Chemistry
DOIs
Publication statusAccepted/In press - 2016

Fingerprint

Ships
Metals
Struts
Nickel
Zinc
Nitrogen
Chemical analysis

Keywords

  • Carboxylate ligands
  • Coordination modes
  • Metal-organic frameworks
  • Synthesis design
  • Transmetalation

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

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abstract = "A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.",
keywords = "Carboxylate ligands, Coordination modes, Metal-organic frameworks, Synthesis design, Transmetalation",
author = "Yan Xu and Vermeulen, {Nicolaas A.} and Yangyang Liu and Hupp, {Joseph T} and Farha, {Omar K.}",
year = "2016",
doi = "10.1002/ejic.201600069",
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T1 - SALE-Ing a MOF-Based "Ship of Theseus." Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

AU - Xu, Yan

AU - Vermeulen, Nicolaas A.

AU - Liu, Yangyang

AU - Hupp, Joseph T

AU - Farha, Omar K.

PY - 2016

Y1 - 2016

N2 - A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.

AB - A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit - the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node - of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.

KW - Carboxylate ligands

KW - Coordination modes

KW - Metal-organic frameworks

KW - Synthesis design

KW - Transmetalation

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