Scattering theory and dynamics

Time-dependent and time-independent methods

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

This paper overviews the uses of scattering theory in physical chemistry, with emphasis on bimolecular chemical reactions. The topic is introduced with a historical survey of theoretical work on the H + H2 reaction. Then several of the most commonly used methods are described, including time-independent and time-dependent quantum methods, approximate quantum methods, and semiclassical and classical methods. The applications of these methods to three benchmark atom-diatom reactions, F + H2, I + HI, and H + O2, are considered in detail. These and the H + H2 application are used to illustrate dynamical phenomena that are important in chemical processes, including tunneling, trapped state resonances, quantized transition states, energy partitioning, angular distributions, and geometric phase effects. Connections with molecular beam, photodetachment, and laser chemistry experiments are discussed. Other scattering theory applications, including electronically nonadiabatic reactions, reactions with four or more atoms, photodissociation processes, and condensed phase and surface reactions, are briefly mentioned.

Original languageEnglish
Pages (from-to)12839-12847
Number of pages9
JournalJournal of Physical Chemistry
Volume100
Issue number31
Publication statusPublished - Aug 1 1996

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Scattering
Laser chemistry
scattering
Photodissociation
Physical chemistry
Atoms
Electron tunneling
Molecular beams
Angular distribution
Surface reactions
Electron transitions
Electron energy levels
Chemical reactions
photodetachment
physical chemistry
algae
photodissociation
surface reactions
molecular beams
atoms

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Engineering(all)

Cite this

Scattering theory and dynamics : Time-dependent and time-independent methods. / Schatz, George C.

In: Journal of Physical Chemistry, Vol. 100, No. 31, 01.08.1996, p. 12839-12847.

Research output: Contribution to journalArticle

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