Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate

Galia Maayan; Benjamin Ganchegui; Walter Leitner; Ronny Neumann

doi:10.1039/b603148j

Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H₅PV₂Mo₁₀O₄₀ polyoxometalate

Galia Maayan, Benjamin Ganchegui, Walter Leitner, Ronny Neumann

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Selective aerobic oxidation of benzylic alcohols and of activated aromatic hydrocarbons occurs in supercritical CO₂ as reaction medium using H₅PV₂Mo₁₀O₄₀ as a quasi-heterogeneous catalyst without further additives or co-solvents; efficient recycling is possible and no metal leaching is detectable in the product stream.

Original language	English
Pages (from-to)	2230-2232
Number of pages	3
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/b603148j
Publication status	Published - Jan 1 2006

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Selective aerobic oxidation of benzylic alcohols and of activated aromatic hydrocarbons occurs in supercritical CO2 as reaction medium using H5PV2Mo10O40 as a quasi-heterogeneous catalyst without further additives or co-solvents; efficient recycling is possible and no metal leaching is detectable in the product stream.",

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