Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Tendai Gadzikwa, Omar K. Farha, Christos D. Malliakas, Mercouri G Kanatzidis, Joseph T Hupp, SonBinh T. Nguyen

Research output: Contribution to journalArticle

173 Citations (Scopus)

Abstract

(Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

Original languageEnglish
Pages (from-to)13613-13615
Number of pages3
JournalJournal of the American Chemical Society
Volume131
Issue number38
DOIs
Publication statusPublished - 2009

Fingerprint

Click Chemistry
Bearings (structural)
Metals
Alkynes
Azides
Acetylene
Porous materials
Crystals

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry. / Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.; Kanatzidis, Mercouri G; Hupp, Joseph T; Nguyen, SonBinh T.

In: Journal of the American Chemical Society, Vol. 131, No. 38, 2009, p. 13613-13615.

Research output: Contribution to journalArticle

Gadzikwa, Tendai ; Farha, Omar K. ; Malliakas, Christos D. ; Kanatzidis, Mercouri G ; Hupp, Joseph T ; Nguyen, SonBinh T. / Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 38. pp. 13613-13615.
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