Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier

Amit Kumar, Trevor Janes, Noel Angel Espinosa-Jalapa, David Milstein

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%.

Original languageEnglish
Pages (from-to)7453-7457
Number of pages5
JournalJournal of the American Chemical Society
Volume140
Issue number24
DOIs
Publication statusPublished - Jun 20 2018

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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