Abstract
Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%.
| Original language | English |
|---|---|
| Pages (from-to) | 7453-7457 |
| Number of pages | 5 |
| Journal | Journal of the American Chemical Society |
| Volume | 140 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Jun 20 2018 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier. / Kumar, Amit; Janes, Trevor; Espinosa-Jalapa, Noel Angel; Milstein, David.
In: Journal of the American Chemical Society, Vol. 140, No. 24, 20.06.2018, p. 7453-7457.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier
AU - Kumar, Amit
AU - Janes, Trevor
AU - Espinosa-Jalapa, Noel Angel
AU - Milstein, David
PY - 2018/6/20
Y1 - 2018/6/20
N2 - Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%.
AB - Direct hydrogenation of a broad variety of cyclic imides to diols and amines using a ruthenium catalyst is reported here. We have applied this strategy toward the development of a new liquid organic hydrogen carrier system based on the hydrogenation of bis-cyclic imide that is formed by the dehydrogenative coupling of 1,4-butanediol and ethylenediamine using a new ruthenium catalyst. The rechargeable system has a maximum gravimetric hydrogen storage capacity of 6.66 wt%.
UR - http://www.scopus.com/inward/record.url?scp=85048005889&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85048005889&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b04581
DO - 10.1021/jacs.8b04581
M3 - Article
VL - 140
SP - 7453
EP - 7457
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 24
ER -