Abstract
In this review, the authors summarize some of the recent advances in the understanding of factors that determine selectivity in the selective oxidation of hydrocarbons. Although most of the discussions involve the oxidative dehydrogenation of butene to butadiene on ferrite catalysts, the principles are applicable to other oxidation systems. In this regard, it has been demonstrated that the selectivity depends on a variety of factors ranging from the nature of the transition metal ion which determines the interaction of butene and butadiene on the catalyst and the ability to activate gaseous oxygen to form a highly reactive surface species, the crystal structure which determines the reduction and oxidation properties, the crystallite size, and the orientation of the exposed crystal planes.
| Original language | English |
|---|---|
| Title of host publication | Advances in Catalysis |
| Publisher | Academic Press Inc |
| Pages | 159-198 |
| Number of pages | 40 |
| Volume | 33 |
| ISBN (Print) | 0120078333 |
| Publication status | Published - 1985 |
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ASJC Scopus subject areas
- Engineering(all)
- Catalysis
- Chemistry(all)
Cite this
SELECTIVE OXIDATIVE DEHYDROGENATION OF BUTENES ON FERRITE CATALYSTS. / Kung, Harold H; Kung, Mayfair C.
Advances in Catalysis. Vol. 33 Academic Press Inc, 1985. p. 159-198.Research output: Chapter in Book/Report/Conference proceeding › Chapter
}
TY - CHAP
T1 - SELECTIVE OXIDATIVE DEHYDROGENATION OF BUTENES ON FERRITE CATALYSTS.
AU - Kung, Harold H
AU - Kung, Mayfair C.
PY - 1985
Y1 - 1985
N2 - In this review, the authors summarize some of the recent advances in the understanding of factors that determine selectivity in the selective oxidation of hydrocarbons. Although most of the discussions involve the oxidative dehydrogenation of butene to butadiene on ferrite catalysts, the principles are applicable to other oxidation systems. In this regard, it has been demonstrated that the selectivity depends on a variety of factors ranging from the nature of the transition metal ion which determines the interaction of butene and butadiene on the catalyst and the ability to activate gaseous oxygen to form a highly reactive surface species, the crystal structure which determines the reduction and oxidation properties, the crystallite size, and the orientation of the exposed crystal planes.
AB - In this review, the authors summarize some of the recent advances in the understanding of factors that determine selectivity in the selective oxidation of hydrocarbons. Although most of the discussions involve the oxidative dehydrogenation of butene to butadiene on ferrite catalysts, the principles are applicable to other oxidation systems. In this regard, it has been demonstrated that the selectivity depends on a variety of factors ranging from the nature of the transition metal ion which determines the interaction of butene and butadiene on the catalyst and the ability to activate gaseous oxygen to form a highly reactive surface species, the crystal structure which determines the reduction and oxidation properties, the crystallite size, and the orientation of the exposed crystal planes.
UR - http://www.scopus.com/inward/record.url?scp=0022274595&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0022274595&partnerID=8YFLogxK
M3 - Chapter
AN - SCOPUS:0022274595
SN - 0120078333
VL - 33
SP - 159
EP - 198
BT - Advances in Catalysis
PB - Academic Press Inc
ER -