Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks

Marianne B. Lalonde, Joseph E. Mondloch, Pravas Deria, Amy A. Sarjeant, Salih S. Al-Juaid, Osman I. Osman, Omar K. Farha, Joseph T Hupp

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Solvent-assisted linker exchange (SALE) has recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.

Original languageEnglish
Pages (from-to)7142-7144
Number of pages3
JournalInorganic Chemistry
Volume54
Issue number15
DOIs
Publication statusPublished - Aug 3 2015

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Coordination Complexes
Hydrophobicity
hydrophobicity
organic materials
metals
Gases
Metals
vapor phases
synthesis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Lalonde, M. B., Mondloch, J. E., Deria, P., Sarjeant, A. A., Al-Juaid, S. S., Osman, O. I., ... Hupp, J. T. (2015). Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks. Inorganic Chemistry, 54(15), 7142-7144. https://doi.org/10.1021/acs.inorgchem.5b01231

Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks. / Lalonde, Marianne B.; Mondloch, Joseph E.; Deria, Pravas; Sarjeant, Amy A.; Al-Juaid, Salih S.; Osman, Osman I.; Farha, Omar K.; Hupp, Joseph T.

In: Inorganic Chemistry, Vol. 54, No. 15, 03.08.2015, p. 7142-7144.

Research output: Contribution to journalArticle

Lalonde, MB, Mondloch, JE, Deria, P, Sarjeant, AA, Al-Juaid, SS, Osman, OI, Farha, OK & Hupp, JT 2015, 'Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks', Inorganic Chemistry, vol. 54, no. 15, pp. 7142-7144. https://doi.org/10.1021/acs.inorgchem.5b01231
Lalonde MB, Mondloch JE, Deria P, Sarjeant AA, Al-Juaid SS, Osman OI et al. Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks. Inorganic Chemistry. 2015 Aug 3;54(15):7142-7144. https://doi.org/10.1021/acs.inorgchem.5b01231
Lalonde, Marianne B. ; Mondloch, Joseph E. ; Deria, Pravas ; Sarjeant, Amy A. ; Al-Juaid, Salih S. ; Osman, Osman I. ; Farha, Omar K. ; Hupp, Joseph T. / Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks. In: Inorganic Chemistry. 2015 ; Vol. 54, No. 15. pp. 7142-7144.
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