Abstract
(Chemical Equation Presented) Air stable and waterproof: Selective and efficient synthesis of primary amines directly from alcohols and ammonia is achieved under mild conditions (see scheme). The reaction is homogenously catalyzed by a novel air-stable ruthenium pincer complex and can proceed in toluene or even in the absence of solvent or "on water".
| Original language | English |
|---|---|
| Pages (from-to) | 8661-8664 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 45 |
| DOIs | |
| Publication status | Published - Oct 27 2008 |
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Keywords
- Amines
- Homogeneous catalysis
- Pincer ligands
- Ruthenium
- Synthetic methods
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Selective synthesis of primary amines directly from alcohols and ammonia. / Gunanathan, Chidambaram; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 47, No. 45, 27.10.2008, p. 8661-8664.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Selective synthesis of primary amines directly from alcohols and ammonia
AU - Gunanathan, Chidambaram
AU - Milstein, David
PY - 2008/10/27
Y1 - 2008/10/27
N2 - (Chemical Equation Presented) Air stable and waterproof: Selective and efficient synthesis of primary amines directly from alcohols and ammonia is achieved under mild conditions (see scheme). The reaction is homogenously catalyzed by a novel air-stable ruthenium pincer complex and can proceed in toluene or even in the absence of solvent or "on water".
AB - (Chemical Equation Presented) Air stable and waterproof: Selective and efficient synthesis of primary amines directly from alcohols and ammonia is achieved under mild conditions (see scheme). The reaction is homogenously catalyzed by a novel air-stable ruthenium pincer complex and can proceed in toluene or even in the absence of solvent or "on water".
KW - Amines
KW - Homogeneous catalysis
KW - Pincer ligands
KW - Ruthenium
KW - Synthetic methods
UR - http://www.scopus.com/inward/record.url?scp=55249090662&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=55249090662&partnerID=8YFLogxK
U2 - 10.1002/anie.200803229
DO - 10.1002/anie.200803229
M3 - Article
C2 - 18846519
AN - SCOPUS:55249090662
VL - 47
SP - 8661
EP - 8664
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 45
ER -