Selectivity for dimers in pentene oligomerization over acid zeolites

Atish Kulkarni; Akshai Kumar; Alan S. Goldman; Fuat E. Celik

doi:10.1016/j.catcom.2015.11.012

Selectivity for dimers in pentene oligomerization over acid zeolites

Atish Kulkarni, Akshai Kumar, Alan S. Goldman, Fuat E. Celik

Rutgers University

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered rings (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C₁₀ olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.

Original language	English
Pages (from-to)	98-102
Number of pages	5
Journal	Catalysis Communications
Volume	75
DOIs	https://doi.org/10.1016/j.catcom.2015.11.012
Publication status	Published - Feb 5 2016

Keywords

1-pentene
Cracking
Dimerization
Ferrierite
Oligomerization
Zeolite

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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title = "Selectivity for dimers in pentene oligomerization over acid zeolites",

abstract = "The reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered rings (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C10 olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.",

keywords = "1-pentene, Cracking, Dimerization, Ferrierite, Oligomerization, Zeolite",

author = "Atish Kulkarni and Akshai Kumar and Goldman, {Alan S.} and Celik, {Fuat E.}",

note = "Funding Information: This work was supported by NSF under the CCI Center for Enabling New Technologies through Catalysis (CENTC) Phase II Renewal, CHE-1205189 . ",

year = "2016",

month = feb,

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doi = "10.1016/j.catcom.2015.11.012",

language = "English",

volume = "75",

pages = "98--102",

journal = "Catalysis Communications",

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TY - JOUR

T1 - Selectivity for dimers in pentene oligomerization over acid zeolites

AU - Kulkarni, Atish

AU - Kumar, Akshai

AU - Goldman, Alan S.

AU - Celik, Fuat E.

N1 - Funding Information: This work was supported by NSF under the CCI Center for Enabling New Technologies through Catalysis (CENTC) Phase II Renewal, CHE-1205189 .

PY - 2016/2/5

Y1 - 2016/2/5

N2 - The reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered rings (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C10 olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.

AB - The reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered rings (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C10 olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.

KW - 1-pentene

KW - Cracking

KW - Dimerization

KW - Ferrierite

KW - Oligomerization

KW - Zeolite

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DO - 10.1016/j.catcom.2015.11.012

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VL - 75

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EP - 102

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -

Selectivity for dimers in pentene oligomerization over acid zeolites

Abstract

Keywords

ASJC Scopus subject areas

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