Abstract
Small- and wide-angle X-ray scattering in solution reveals that chlorophyll (Chl) trefoils self-assemble in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) to yield supramolecular cyclic trimers. Two Chls of each trefoil coordinate to DABCO to form the vertices of the hexagonal structure, while the remaining Chl acts like a substituent on the benzene-like assembly.
| Original language | English |
|---|---|
| Pages (from-to) | 401-403 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 2010 |
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ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Self-assembly of a hexagonal supramolecular light-harvesting array from chlorophyll a trefoil building blocks. / Gunderson, Victoria L.; Mickley Conron, Sarah M.; Wasielewski, Michael R.
In: Chemical Communications, Vol. 46, No. 3, 2010, p. 401-403.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Self-assembly of a hexagonal supramolecular light-harvesting array from chlorophyll a trefoil building blocks
AU - Gunderson, Victoria L.
AU - Mickley Conron, Sarah M.
AU - Wasielewski, Michael R
PY - 2010
Y1 - 2010
N2 - Small- and wide-angle X-ray scattering in solution reveals that chlorophyll (Chl) trefoils self-assemble in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) to yield supramolecular cyclic trimers. Two Chls of each trefoil coordinate to DABCO to form the vertices of the hexagonal structure, while the remaining Chl acts like a substituent on the benzene-like assembly.
AB - Small- and wide-angle X-ray scattering in solution reveals that chlorophyll (Chl) trefoils self-assemble in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) to yield supramolecular cyclic trimers. Two Chls of each trefoil coordinate to DABCO to form the vertices of the hexagonal structure, while the remaining Chl acts like a substituent on the benzene-like assembly.
UR - http://www.scopus.com/inward/record.url?scp=75649089650&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=75649089650&partnerID=8YFLogxK
U2 - 10.1039/b921084a
DO - 10.1039/b921084a
M3 - Article
C2 - 20066305
AN - SCOPUS:75649089650
VL - 46
SP - 401
EP - 403
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 3
ER -