Self-Healing Inside APbBr3 Halide Perovskite Crystals

Davide Raffaele Ceratti, Yevgeny Rakita, Llorenç Cremonesi, Ron Tenne, Vyacheslav Kalchenko, Michael Elbaum, Dan Oron, Marco Alberto Carlo Potenza, Gary Hodes, David Cahen

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Self-healing, where a modification in some parameter is reversed with time without any external intervention, is one of the particularly interesting properties of halide perovskites. While there are a number of studies showing such self-healing in perovskites, they all are carried out on thin films, where the interface between the perovskite and another phase (including the ambient) is often a dominating and interfering factor in the process. Here, self-healing in perovskite (methylammonium, formamidinium, and cesium lead bromide (MAPbBr3, FAPbBr3, and CsPbBr3)) single crystals is reported, using two-photon microscopy to create damage (photobleaching) ≈110 µm inside the crystals and to monitor the recovery of photoluminescence after the damage. Self-healing occurs in all three perovskites with FAPbBr3 the fastest (≈1 h) and CsPbBr3 the slowest (tens of hours) to recover. This behavior, different from surface-dominated stability trends, is typical of the bulk and is strongly dependent on the localization of degradation products not far from the site of the damage. The mechanism of self-healing is discussed with the possible participation of polybromide species. It provides a closed chemical cycle and does not necessarily involve defect or ion migration phenomena that are often proposed to explain reversible phenomena in halide perovskites.

Original languageEnglish
Article number1706273
JournalAdvanced Materials
Volume30
Issue number10
DOIs
Publication statusPublished - Mar 8 2018

Fingerprint

Perovskite
Photobleaching
Cesium
Crystals
Photoluminescence
Microscopic examination
Photons
Lead
Single crystals
Ions
Recovery
Degradation
Thin films
Defects
perovskite
methylamine
formamidine
lead bromide

Keywords

  • bleaching
  • halide perovskites
  • photoluminescence
  • self-healing
  • self-repair

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Ceratti, D. R., Rakita, Y., Cremonesi, L., Tenne, R., Kalchenko, V., Elbaum, M., ... Cahen, D. (2018). Self-Healing Inside APbBr3 Halide Perovskite Crystals. Advanced Materials, 30(10), [1706273]. https://doi.org/10.1002/adma.201706273

Self-Healing Inside APbBr3 Halide Perovskite Crystals. / Ceratti, Davide Raffaele; Rakita, Yevgeny; Cremonesi, Llorenç; Tenne, Ron; Kalchenko, Vyacheslav; Elbaum, Michael; Oron, Dan; Potenza, Marco Alberto Carlo; Hodes, Gary; Cahen, David.

In: Advanced Materials, Vol. 30, No. 10, 1706273, 08.03.2018.

Research output: Contribution to journalArticle

Ceratti, DR, Rakita, Y, Cremonesi, L, Tenne, R, Kalchenko, V, Elbaum, M, Oron, D, Potenza, MAC, Hodes, G & Cahen, D 2018, 'Self-Healing Inside APbBr3 Halide Perovskite Crystals', Advanced Materials, vol. 30, no. 10, 1706273. https://doi.org/10.1002/adma.201706273
Ceratti DR, Rakita Y, Cremonesi L, Tenne R, Kalchenko V, Elbaum M et al. Self-Healing Inside APbBr3 Halide Perovskite Crystals. Advanced Materials. 2018 Mar 8;30(10). 1706273. https://doi.org/10.1002/adma.201706273
Ceratti, Davide Raffaele ; Rakita, Yevgeny ; Cremonesi, Llorenç ; Tenne, Ron ; Kalchenko, Vyacheslav ; Elbaum, Michael ; Oron, Dan ; Potenza, Marco Alberto Carlo ; Hodes, Gary ; Cahen, David. / Self-Healing Inside APbBr3 Halide Perovskite Crystals. In: Advanced Materials. 2018 ; Vol. 30, No. 10.
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