Abstract
Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.
| Original language | English |
|---|---|
| Pages (from-to) | 5961-5963 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 43 |
| Issue number | 44 |
| DOIs | |
| Publication status | Published - Nov 12 2004 |
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Keywords
- C-O activation
- Iridium
- Quinones
- Rhodium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. / van der Boom, Milko; Zubkov, Tatiana; Shukla, Atindra D.; Rybtchinski, Boris; Shimon, Linda J W; Rozenberg, Haim; Ben-David, Yehoshoa; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 43, No. 44, 12.11.2004, p. 5961-5963.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Self-oxidation of a phenolate complex to a bimetallic stilbene quinone
AU - van der Boom, Milko
AU - Zubkov, Tatiana
AU - Shukla, Atindra D.
AU - Rybtchinski, Boris
AU - Shimon, Linda J W
AU - Rozenberg, Haim
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2004/11/12
Y1 - 2004/11/12
N2 - Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.
AB - Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.
KW - C-O activation
KW - Iridium
KW - Quinones
KW - Rhodium
UR - http://www.scopus.com/inward/record.url?scp=9344271164&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=9344271164&partnerID=8YFLogxK
U2 - 10.1002/anie.200460360
DO - 10.1002/anie.200460360
M3 - Article
C2 - 15547905
AN - SCOPUS:9344271164
VL - 43
SP - 5961
EP - 5963
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 44
ER -