Self-oxidation of a phenolate complex to a bimetallic stilbene quinone

Milko E. Van Der Boom; Tatiana Zubkov; Atindra D. Shukla; Boris Rybtchinski; Linda J.W. Shimon; Haim Rozenberg; Yehoshoa Ben-David; David Milstein

doi:10.1002/anie.200460360

Self-oxidation of a phenolate complex to a bimetallic stilbene quinone

Milko E. Van Der Boom, Tatiana Zubkov, Atindra D. Shukla, Boris Rybtchinski, Linda J.W. Shimon, Haim Rozenberg, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Do-it-yourself oxidation: The Rh^III complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n²-coordinated to the metal centers.

Original language	English
Pages (from-to)	5961-5963
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	44
DOIs	https://doi.org/10.1002/anie.200460360
Publication status	Published - Nov 12 2004

Fingerprint

Keywords

C-O activation
Iridium
Quinones
Rhodium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Van Der Boom, M. E., Zubkov, T., Shukla, A. D., Rybtchinski, B., Shimon, L. J. W., Rozenberg, H., Ben-David, Y., & Milstein, D. (2004). Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. Angewandte Chemie - International Edition, 43(44), 5961-5963. https://doi.org/10.1002/anie.200460360

Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. / Van Der Boom, Milko E.; Zubkov, Tatiana; Shukla, Atindra D.; Rybtchinski, Boris; Shimon, Linda J.W.; Rozenberg, Haim; Ben-David, Yehoshoa; Milstein, David.

In: Angewandte Chemie - International Edition, Vol. 43, No. 44, 12.11.2004, p. 5961-5963.

Research output: Contribution to journal › Article

@article{e8a1fe07c25b4906a71b73fbaba8d27e,

title = "Self-oxidation of a phenolate complex to a bimetallic stilbene quinone",

abstract = "Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.",

keywords = "C-O activation, Iridium, Quinones, Rhodium",

author = "{Van Der Boom}, {Milko E.} and Tatiana Zubkov and Shukla, {Atindra D.} and Boris Rybtchinski and Shimon, {Linda J.W.} and Haim Rozenberg and Yehoshoa Ben-David and David Milstein",

year = "2004",

month = nov

day = "12",

doi = "10.1002/anie.200460360",

language = "English",

volume = "43",

pages = "5961--5963",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "44",

}

TY - JOUR

T1 - Self-oxidation of a phenolate complex to a bimetallic stilbene quinone

AU - Van Der Boom, Milko E.

AU - Zubkov, Tatiana

AU - Shukla, Atindra D.

AU - Rybtchinski, Boris

AU - Shimon, Linda J.W.

AU - Rozenberg, Haim

AU - Ben-David, Yehoshoa

AU - Milstein, David

PY - 2004/11/12

Y1 - 2004/11/12

N2 - Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.

AB - Do-it-yourself oxidation: The RhIII complex 1 undergoes a self-oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 (2:3 = 1:3). This reaction involves cleavage of a strong aryl-oxygen bond. X-ray analysis of 2 reveals that the two quinonoid C=O bonds are n2-coordinated to the metal centers.

KW - C-O activation

KW - Iridium

KW - Quinones

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=9344271164&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=9344271164&partnerID=8YFLogxK

U2 - 10.1002/anie.200460360

DO - 10.1002/anie.200460360

M3 - Article

C2 - 15547905

AN - SCOPUS:9344271164

VL - 43

SP - 5961

EP - 5963

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 44

ER -

Access to Document

10.1002/anie.200460360