Abstract
Photochemical hydrogen evolution from a UiO-66-incorporated Fe2(dcbdt)(CO)6 catalyst in conjunction with a ruthenium photosensitizer and an ascorbate donor ceases after a period of irradiation, but is restored after a 60 min. resting period in the dark. Control experiments show that neither product inhibition nor pore clogging is responsible for this surprising behaviour, and intra-crystal linker scrambling is proposed as a potential explanation.
Original language | English |
---|---|
Pages (from-to) | 287-290 |
Number of pages | 4 |
Journal | ChemPhotoChem |
Volume | 4 |
Issue number | 4 |
DOIs | |
Publication status | Published - Apr 1 2020 |
Keywords
- diiron catalyst
- hydrogen production
- hydrogenase mimics
- metal-organic framework
- photocatalysis
- self-recovery
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Analytical Chemistry