Semiconductor physics of organic–inorganic 2D halide perovskites

Jean Christophe Blancon, Jacky Even, Costas C. Stoumpos, Mercouri G. Kanatzidis, Aditya D. Mohite

Research output: Contribution to journalReview articlepeer-review

Abstract

Achieving technologically relevant performance and stability for optoelectronics, energy conversion, photonics, spintronics and quantum devices requires creating atomically precise materials with tailored homo- and hetero-interfaces, which can form functional hierarchical assemblies. Nature employs tunable sequence chemistry to create complex architectures, which efficiently transform matter and energy, however, in contrast, the design of synthetic materials and their integration remains a long-standing challenge. Organic–inorganic two-dimensional halide perovskites (2DPKs) are organic and inorganic two-dimensional layers, which self-assemble in solution to form highly ordered periodic stacks. They exhibit a large compositional and structural phase space, which has led to novel and exciting physical properties. In this Review, we discuss the current understanding in the structure and physical properties of 2DPKs from the monolayers to assemblies, and present a comprehensive comparison with conventional semiconductors, thereby providing a broad understanding of low-dimensional semiconductors that feature complex organic–inorganic hetero-interfaces.

Original languageEnglish
Pages (from-to)969-985
Number of pages17
JournalNature nanotechnology
Volume15
Issue number12
DOIs
Publication statusPublished - Dec 2020

ASJC Scopus subject areas

  • Bioengineering
  • Atomic and Molecular Physics, and Optics
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

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