Separation of hydrocarbons with a microporous metal-organic framework

Long Pan; David H. Olson; Lauren R. Ciemnolonski; Ryan Heady; Jing Li

doi:10.1002/anie.200503503

Separation of hydrocarbons with a microporous metal-organic framework

Long Pan, David H. Olson, Lauren R. Ciemnolonski, Ryan Heady, Jing Li

Rutgers University

Research output: Contribution to journal › Article

659 Citations (Scopus)

Abstract

Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H₂hfipbb)_0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 4⁴ nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C ₂, C₃, and n-C₄ olefins and alkanes (see picture). (Figure Presented)

Original language	English
Pages (from-to)	616-619
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	4
DOIs	https://doi.org/10.1002/anie.200503503
Publication status	Published - Jan 16 2006

Keywords

Adsorption
Hydrocarbons
Hydrothermal synthesis
Microporous materials

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200503503

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Pan, L., Olson, D. H., Ciemnolonski, L. R., Heady, R., & Li, J. (2006). Separation of hydrocarbons with a microporous metal-organic framework. Angewandte Chemie - International Edition, 45(4), 616-619. https://doi.org/10.1002/anie.200503503

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AU - Olson, David H.

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AU - Heady, Ryan

AU - Li, Jing

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AB - Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H2hfipbb)0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 44 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C 2, C3, and n-C4 olefins and alkanes (see picture). (Figure Presented)

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KW - Hydrocarbons

KW - Hydrothermal synthesis

KW - Microporous materials

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