Separation of hydrocarbons with a microporous metal-organic framework

Long Pan; David H. Olson; Lauren R. Ciemnolonski; Ryan Heady; Jing Li

doi:10.1002/anie.200503503

Separation of hydrocarbons with a microporous metal-organic framework

Long Pan, David H. Olson, Lauren R. Ciemnolonski, Ryan Heady, Jing Li

Rutgers University

Research output: Contribution to journal › Article

654 Citations (Scopus)

Abstract

Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H₂hfipbb)_0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 4⁴ nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C ₂, C₃, and n-C₄ olefins and alkanes (see picture). (Figure Presented)

Original language	English
Pages (from-to)	616-619
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	4
DOIs	https://doi.org/10.1002/anie.200503503
Publication status	Published - Jan 16 2006

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Keywords

Adsorption
Hydrocarbons
Hydrothermal synthesis
Microporous materials

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Pan, L., Olson, D. H., Ciemnolonski, L. R., Heady, R., & Li, J. (2006). Separation of hydrocarbons with a microporous metal-organic framework. Angewandte Chemie - International Edition, 45(4), 616-619. https://doi.org/10.1002/anie.200503503

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Access to Document

10.1002/anie.200503503