Sequence-dependent assembly to control molecular interface properties

Graham De Ruiter, Michal Lahav, Hodaya Keisar, Milko van der Boom

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence-dependent assembly strategy has implications for various disciplines that involve self-assembly.

Original languageEnglish
Pages (from-to)704-709
Number of pages6
JournalAngewandte Chemie - International Edition
Volume52
Issue number2
DOIs
Publication statusPublished - Jan 7 2013

Fingerprint

Charge trapping
Coordination Complexes
Metal complexes
Electrochemical properties
Self assembly
Electrons

Keywords

  • electrochemistry
  • interfaces
  • metal complexes
  • molecular materials
  • sequence-dependent assembly

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Sequence-dependent assembly to control molecular interface properties. / De Ruiter, Graham; Lahav, Michal; Keisar, Hodaya; van der Boom, Milko.

In: Angewandte Chemie - International Edition, Vol. 52, No. 2, 07.01.2013, p. 704-709.

Research output: Contribution to journalArticle

De Ruiter, Graham ; Lahav, Michal ; Keisar, Hodaya ; van der Boom, Milko. / Sequence-dependent assembly to control molecular interface properties. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 2. pp. 704-709.
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