Abstract
Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence-dependent assembly strategy has implications for various disciplines that involve self-assembly.
| Original language | English |
|---|---|
| Pages (from-to) | 704-709 |
| Number of pages | 6 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 7 2013 |
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Keywords
- electrochemistry
- interfaces
- metal complexes
- molecular materials
- sequence-dependent assembly
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Sequence-dependent assembly to control molecular interface properties. / De Ruiter, Graham; Lahav, Michal; Keisar, Hodaya; van der Boom, Milko.
In: Angewandte Chemie - International Edition, Vol. 52, No. 2, 07.01.2013, p. 704-709.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Sequence-dependent assembly to control molecular interface properties
AU - De Ruiter, Graham
AU - Lahav, Michal
AU - Keisar, Hodaya
AU - van der Boom, Milko
PY - 2013/1/7
Y1 - 2013/1/7
N2 - Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence-dependent assembly strategy has implications for various disciplines that involve self-assembly.
AB - Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence-dependent assembly strategy has implications for various disciplines that involve self-assembly.
KW - electrochemistry
KW - interfaces
KW - metal complexes
KW - molecular materials
KW - sequence-dependent assembly
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U2 - 10.1002/anie.201207467
DO - 10.1002/anie.201207467
M3 - Article
VL - 52
SP - 704
EP - 709
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 2
ER -