Signatures of excitons and polaron pairs in the femtosecond excited-state absorption spectra of phenylene-based conjugated polymers and oligomers

D. W. McBranch, B. Kraabel, S. Xu, R. S. Kohlman, Victor I Klimov, D. D C Bradley, B. R. Hsieh, M. Rubner

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

We present results of broadband femtosecond transient absorption measurements in thin films of several phenylene-based π-conjugated materials. We compare results for unsubstituted poly(phenylene vinylene) (PPV), polyfluorene, and a substituted five-ring oligomer of PPV. We observe universal spectral features in all materials, implying a common origin for the photoexcited species in all members of this family. In each material, we observe two photoinduced absorption (PA) features in the visible region in addition to a stimulated emission (SE) feature. The first PA feature shows strong dependence of the dynamics on excitation intensity, and correlates precisely with the SE feature, proving that this feature is due to the primary emissive exciton. The second PA feature shows dynamics independent of intensity. In the oligomers, this feature grows quadratically with respect to the first PA feature, as a result of nonlinear interactions of the primary excitons. In the polymers, however, the second feature grows linearly with intensity, and indicates an ultrafast decay channel to nonemissive interchain species due to defects.

Original languageEnglish
Pages (from-to)291-294
Number of pages4
JournalSynthetic Metals
Volume101
Issue number1
DOIs
Publication statusPublished - May 1999

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Gene Conversion
Conjugated polymers
oligomers
Oligomers
Excited states
Excitons
Absorption spectra
Stimulated emission
excitons
signatures
absorption spectra
polymers
excitation
stimulated emission
Polymers
Thin films
Defects
LDS 751
broadband
rings

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Signatures of excitons and polaron pairs in the femtosecond excited-state absorption spectra of phenylene-based conjugated polymers and oligomers. / McBranch, D. W.; Kraabel, B.; Xu, S.; Kohlman, R. S.; Klimov, Victor I; Bradley, D. D C; Hsieh, B. R.; Rubner, M.

In: Synthetic Metals, Vol. 101, No. 1, 05.1999, p. 291-294.

Research output: Contribution to journalArticle

McBranch, D. W. ; Kraabel, B. ; Xu, S. ; Kohlman, R. S. ; Klimov, Victor I ; Bradley, D. D C ; Hsieh, B. R. ; Rubner, M. / Signatures of excitons and polaron pairs in the femtosecond excited-state absorption spectra of phenylene-based conjugated polymers and oligomers. In: Synthetic Metals. 1999 ; Vol. 101, No. 1. pp. 291-294.
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AU - Kohlman, R. S.

AU - Klimov, Victor I

AU - Bradley, D. D C

AU - Hsieh, B. R.

AU - Rubner, M.

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