Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111

Yang Peng, Gadipelli Srinivas, Christopher E. Wilmer, Ibrahim Eryazici, Randall Q. Snurr, Joseph T Hupp, Taner Yildirim, Omar K. Farha

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g -1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

Original languageEnglish
Pages (from-to)2992-2994
Number of pages3
JournalChemical Communications
Volume49
Issue number29
DOIs
Publication statusPublished - Apr 14 2013

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Methane
Isotherms
Metals
Adsorption
Experiments
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111. / Peng, Yang; Srinivas, Gadipelli; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Hupp, Joseph T; Yildirim, Taner; Farha, Omar K.

In: Chemical Communications, Vol. 49, No. 29, 14.04.2013, p. 2992-2994.

Research output: Contribution to journalArticle

Peng, Y, Srinivas, G, Wilmer, CE, Eryazici, I, Snurr, RQ, Hupp, JT, Yildirim, T & Farha, OK 2013, 'Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111', Chemical Communications, vol. 49, no. 29, pp. 2992-2994. https://doi.org/10.1039/c3cc40819a
Peng, Yang ; Srinivas, Gadipelli ; Wilmer, Christopher E. ; Eryazici, Ibrahim ; Snurr, Randall Q. ; Hupp, Joseph T ; Yildirim, Taner ; Farha, Omar K. / Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111. In: Chemical Communications. 2013 ; Vol. 49, No. 29. pp. 2992-2994.
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