Single carbon nanotubes probed by photoluminescence excitation spectroscopy

The role of phonon-assisted transitions

H. Htoon, M. J. O'Connell, S. K. Doom, Victor I Klimov

Research output: Contribution to journalArticle

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Abstract

We study light absorption mechanisms in semiconducting carbon nanotubes using low-temperature, single-nanotube photoluminescence excitation spectroscopy. In addition to purely electronic transitions, we observe several strong phonon-assisted bands due to excitation of one or more phonon modes together with the first electronic state. In contrast with a small width of emission lines (sub-meV to a few meV), most of the photoluminescence excitation features have significant linewidths of tens of meV. All of these observations indicate very strong electron-phonon coupling that allows efficient excitation of electronic states via phonon-assisted processes and leads to ultrafast intraband relaxation due to inelastic electron-phonon scattering.

Original languageEnglish
Article number127403
JournalPhysical Review Letters
Volume94
Issue number12
DOIs
Publication statusPublished - Apr 1 2005

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carbon nanotubes
photoluminescence
spectroscopy
excitation
electronics
electromagnetic absorption
nanotubes
electrons
scattering

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Single carbon nanotubes probed by photoluminescence excitation spectroscopy : The role of phonon-assisted transitions. / Htoon, H.; O'Connell, M. J.; Doom, S. K.; Klimov, Victor I.

In: Physical Review Letters, Vol. 94, No. 12, 127403, 01.04.2005.

Research output: Contribution to journalArticle

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