Single crystal Cu2O photovoltaics by the floating zone method

Stefan T. Omelchenko, Yulia Tolstova, Samantha S. Wilson, Harry A. Atwater, Nathan S Lewis

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Cu2O is a p-type semiconductor with desirable bulk properties for photovoltaics. However, the lack of an n-type dopant and surface instability have hindered the development of a high efficiency Cu2O device. In this work, the floating zone method is used to grow high quality single crystals of Cu2O in order to controllably study the interfacial reactions between Cu2O and its heterojunction partners. While inclusions of CuO are inherent to the floating zone growth process we show that they can be removed by post-annealing with phase purity and crystallinity shown by x-ray diffraction. We discuss the role of CuO inclusions on the electronic properties of single crystal Cu2O wafers using Hall measurements. Changes in the resistivity and mobility due to post-annealing are correlated to changing defect densities obtained from steady-state photoluminescence. The optimization of the Cu2O wafers provides a pathway towards the first float zone single crystal Cu2O photovoltaic device.

Original languageEnglish
Title of host publication2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Print)9781479979448
DOIs
Publication statusPublished - Dec 14 2015
Event42nd IEEE Photovoltaic Specialist Conference, PVSC 2015 - New Orleans, United States
Duration: Jun 14 2015Jun 19 2015

Other

Other42nd IEEE Photovoltaic Specialist Conference, PVSC 2015
CountryUnited States
CityNew Orleans
Period6/14/156/19/15

Fingerprint

Single crystals
Annealing
Defect density
Surface chemistry
Electronic properties
Heterojunctions
Photoluminescence
Diffraction
Doping (additives)
Semiconductor materials
X rays

Keywords

  • Cuprous oxide
  • earth abundant photovoltaic
  • floating zone
  • single crystal

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Electronic, Optical and Magnetic Materials

Cite this

Omelchenko, S. T., Tolstova, Y., Wilson, S. S., Atwater, H. A., & Lewis, N. S. (2015). Single crystal Cu2O photovoltaics by the floating zone method. In 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015 [7355920] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2015.7355920

Single crystal Cu2O photovoltaics by the floating zone method. / Omelchenko, Stefan T.; Tolstova, Yulia; Wilson, Samantha S.; Atwater, Harry A.; Lewis, Nathan S.

2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc., 2015. 7355920.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Omelchenko, ST, Tolstova, Y, Wilson, SS, Atwater, HA & Lewis, NS 2015, Single crystal Cu2O photovoltaics by the floating zone method. in 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015., 7355920, Institute of Electrical and Electronics Engineers Inc., 42nd IEEE Photovoltaic Specialist Conference, PVSC 2015, New Orleans, United States, 6/14/15. https://doi.org/10.1109/PVSC.2015.7355920
Omelchenko ST, Tolstova Y, Wilson SS, Atwater HA, Lewis NS. Single crystal Cu2O photovoltaics by the floating zone method. In 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc. 2015. 7355920 https://doi.org/10.1109/PVSC.2015.7355920
Omelchenko, Stefan T. ; Tolstova, Yulia ; Wilson, Samantha S. ; Atwater, Harry A. ; Lewis, Nathan S. / Single crystal Cu2O photovoltaics by the floating zone method. 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc., 2015.
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