Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet, Samat Tussupbayev, Joshua Borycz, James R. Gallagher, Madelyn M. Stalzer, Jeffrey T. Miller, Laura Gagliardi, Joseph T Hupp, Tobin J Marks, Christopher J. Cramer, Massimiliano Delferro, Omar K. Farha

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

Original languageEnglish
Pages (from-to)15680-15683
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number50
DOIs
Publication statusPublished - Dec 23 2015

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Polymerization
Metals
Catalysts
Discrete Fourier transforms
Scaffolds
Ethylene
ethylene
1-hexene

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Klet, R. C., Tussupbayev, S., Borycz, J., Gallagher, J. R., Stalzer, M. M., Miller, J. T., ... Farha, O. K. (2015). Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. Journal of the American Chemical Society, 137(50), 15680-15683. https://doi.org/10.1021/jacs.5b11350

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. / Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua; Gallagher, James R.; Stalzer, Madelyn M.; Miller, Jeffrey T.; Gagliardi, Laura; Hupp, Joseph T; Marks, Tobin J; Cramer, Christopher J.; Delferro, Massimiliano; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 137, No. 50, 23.12.2015, p. 15680-15683.

Research output: Contribution to journalArticle

Klet, RC, Tussupbayev, S, Borycz, J, Gallagher, JR, Stalzer, MM, Miller, JT, Gagliardi, L, Hupp, JT, Marks, TJ, Cramer, CJ, Delferro, M & Farha, OK 2015, 'Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework', Journal of the American Chemical Society, vol. 137, no. 50, pp. 15680-15683. https://doi.org/10.1021/jacs.5b11350
Klet RC, Tussupbayev S, Borycz J, Gallagher JR, Stalzer MM, Miller JT et al. Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. Journal of the American Chemical Society. 2015 Dec 23;137(50):15680-15683. https://doi.org/10.1021/jacs.5b11350
Klet, Rachel C. ; Tussupbayev, Samat ; Borycz, Joshua ; Gallagher, James R. ; Stalzer, Madelyn M. ; Miller, Jeffrey T. ; Gagliardi, Laura ; Hupp, Joseph T ; Marks, Tobin J ; Cramer, Christopher J. ; Delferro, Massimiliano ; Farha, Omar K. / Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. In: Journal of the American Chemical Society. 2015 ; Vol. 137, No. 50. pp. 15680-15683.
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