Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation

Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument

Jeffrey Camacho-Bunquin, Payoli Aich, Magali Ferrandon, Andrew “Bean” Getsoian, Ujjal Das, Fulya Dogan, Larry A. Curtiss, Jeffrey T. Miller, Christopher L. Marshall, Adam S. Hock, Peter C Stair

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Alkyl-zinc and zinc oxide-type sites were synthesized via atomic layer deposition on high-surface-area silica using an integrated atomic layer deposition-catalysis instrument (I-ALD-CAT). One-cycle ALD experiments using diethylzinc (DEZ) afforded Zn/SiO2 systems that provided key insights into the reactivity and stability of Zn sites as a function of dispersion at the submonolayer level. The I-ALD-CAT tool design allowed for systematic comparison of the reactivity of different grafted zinc sites. Open-shell 16-electron, tricoordinate ethyl zinc-silica sites exhibit higher activity in propane hydrogenation-dehydrogenation compared to 18-electron, tetracoordinate zinc oxide-type centers. Silica surface saturation with Zn(II) sites (∼75% of a monolayer) results in facile zinc agglomeration and catalyst deactivation under reaction conditions. Reduced DEZ dosing coupled with thermal substrate pretreatment techniques (e.g., dehydration under vacuum) resulted in increased Zn dispersion and produced Zn/SiO2 catalysts with improved activity and stability under propylene hydrogenation (200 °C) and propane dehydrogenation (550 °C) conditions.

Original languageEnglish
Pages (from-to)170-182
Number of pages13
JournalJournal of Catalysis
Volume345
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Propane
Atomic layer deposition
Dehydrogenation
dehydrogenation
atomic layer epitaxy
propylene
propane
Silicon Dioxide
Catalysis
Hydrogenation
hydrogenation
Propylene
catalysis
Zinc
reactivity
zinc
Silica
silicon dioxide
Zinc Oxide
catalysts

Keywords

  • Atomic layer deposition
  • Dehydrogenation
  • Hydrogenation
  • Zinc

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation : Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument. / Camacho-Bunquin, Jeffrey; Aich, Payoli; Ferrandon, Magali; “Bean” Getsoian, Andrew; Das, Ujjal; Dogan, Fulya; Curtiss, Larry A.; Miller, Jeffrey T.; Marshall, Christopher L.; Hock, Adam S.; Stair, Peter C.

In: Journal of Catalysis, Vol. 345, 01.01.2017, p. 170-182.

Research output: Contribution to journalArticle

Camacho-Bunquin, Jeffrey ; Aich, Payoli ; Ferrandon, Magali ; “Bean” Getsoian, Andrew ; Das, Ujjal ; Dogan, Fulya ; Curtiss, Larry A. ; Miller, Jeffrey T. ; Marshall, Christopher L. ; Hock, Adam S. ; Stair, Peter C. / Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation : Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument. In: Journal of Catalysis. 2017 ; Vol. 345. pp. 170-182.
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