Site identity and importance in cosubstituted bixbyite In2O3

Karl Rickert, Jeremy Harris, Nazmi Sedefoglu, Hamide Kavak, Donald E. Ellis, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

Abstract

The bixbyite structure of In2O3 has two nonequivalent, 6-coordinate cation sites and, when Sn is doped into In2O3, the Sn prefers the “b-site” and produces a highly conductive material. When divalent/tetravalent cation pairs are cosubstituted into In2O3, however, the conductivity increases to a lesser extent and the site occupancy is less understood. We examine the site occupancy in the MgxIn2−2xSnxO3 and ZnxIn2−2xSnxO3 systems with high resolution X-ray and neutron diffraction and density functional theory computations, respectively. In these sample cases and those that are previously reported in the MxIn2−2xSnxO3 (M = Cu, Ni, or Zn) systems, the solubility limit is greater than 25%, ensuring that the b-site cannot be the exclusively preferred site as it is in Sn:In2O3. Prior to this saturation point, we report that the M2+ cation always has at least a partial occupancy on the d-site and the Sn4+ cation has at least a partial occupancy on the b-site. The energies of formation for these configurations are highly favored, and prefer that the divalent and tetravalent substitutes are adjacent in the crystal lattice, which suggests short range ordering. Diffuse reflectance and 4-point probe measurements of MgxIn2−xSnxO3 demonstrate that it can maintain an optical band gap >2.8 eV while surpassing 1000 S/cm in conductivity. Understanding how multiple constituents occupy the two nonequivalent cation sites can provide information on how to optimize cosubstituted systems to increase Sn solubility while maintaining its dopant nature, achieving maximum conductivity.

Original languageEnglish
Article number47
JournalCrystals
Volume7
Issue number2
DOIs
Publication statusPublished - Feb 9 2017

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Cations
Positive ions
cations
conductivity
solubility
Solubility
Conductive materials
Optical band gaps
energy of formation
Neutron diffraction
crystal lattices
Crystal lattices
Density functional theory
neutron diffraction
Doping (additives)
substitutes
density functional theory
saturation
reflectance
X ray diffraction

Keywords

  • Bixbyite
  • Indium oxide
  • Transparent conducting oxide

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

Rickert, K., Harris, J., Sedefoglu, N., Kavak, H., Ellis, D. E., & Poeppelmeier, K. R. (2017). Site identity and importance in cosubstituted bixbyite In2O3 Crystals, 7(2), [47]. https://doi.org/10.3390/cryst7020047

Site identity and importance in cosubstituted bixbyite In2O3 . / Rickert, Karl; Harris, Jeremy; Sedefoglu, Nazmi; Kavak, Hamide; Ellis, Donald E.; Poeppelmeier, Kenneth R.

In: Crystals, Vol. 7, No. 2, 47, 09.02.2017.

Research output: Contribution to journalArticle

Rickert, K, Harris, J, Sedefoglu, N, Kavak, H, Ellis, DE & Poeppelmeier, KR 2017, 'Site identity and importance in cosubstituted bixbyite In2O3 ', Crystals, vol. 7, no. 2, 47. https://doi.org/10.3390/cryst7020047
Rickert, Karl ; Harris, Jeremy ; Sedefoglu, Nazmi ; Kavak, Hamide ; Ellis, Donald E. ; Poeppelmeier, Kenneth R. / Site identity and importance in cosubstituted bixbyite In2O3 In: Crystals. 2017 ; Vol. 7, No. 2.
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