Abstract
We have performed Langevin dynamics calculations on a one-dimensional model for framework materials, focusing on the conductivity of interacting mobile ions in the presence of Coulombic traps. We observe several interesting phenomena, arising from competition among the three potentials (lattice, ion-ion, ion-trap). Findings of interest include: 1. Generally, the compensator will indeed trap a sufficient number of mobile ions to balance its charge. These ions can exchange, but they are quite well localized by the trap. 2. For incommensurate mobile-ion concentrations, the overall DC conductivity is decreased. 3. For commensurate concentrations, the DC conductivity can actually increase, as the trapping renders the remaining mobile-ion array effectively incommensurate.
| Original language | English |
|---|---|
| Pages (from-to) | 1325-1332 |
| Number of pages | 8 |
| Journal | Solid State Ionics |
| Volume | 9-10 |
| Issue number | PART 2 |
| DOIs | |
| Publication status | Published - 1983 |
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ASJC Scopus subject areas
- Electrochemistry
- Physical and Theoretical Chemistry
- Energy Engineering and Power Technology
- Materials Chemistry
- Condensed Matter Physics
Cite this
Site trapping and commensurability effects in framework solid electrolytes. / Jacobson, S. H.; Ratner, Mark A.
In: Solid State Ionics, Vol. 9-10, No. PART 2, 1983, p. 1325-1332.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Site trapping and commensurability effects in framework solid electrolytes
AU - Jacobson, S. H.
AU - Ratner, Mark A
PY - 1983
Y1 - 1983
N2 - We have performed Langevin dynamics calculations on a one-dimensional model for framework materials, focusing on the conductivity of interacting mobile ions in the presence of Coulombic traps. We observe several interesting phenomena, arising from competition among the three potentials (lattice, ion-ion, ion-trap). Findings of interest include: 1. Generally, the compensator will indeed trap a sufficient number of mobile ions to balance its charge. These ions can exchange, but they are quite well localized by the trap. 2. For incommensurate mobile-ion concentrations, the overall DC conductivity is decreased. 3. For commensurate concentrations, the DC conductivity can actually increase, as the trapping renders the remaining mobile-ion array effectively incommensurate.
AB - We have performed Langevin dynamics calculations on a one-dimensional model for framework materials, focusing on the conductivity of interacting mobile ions in the presence of Coulombic traps. We observe several interesting phenomena, arising from competition among the three potentials (lattice, ion-ion, ion-trap). Findings of interest include: 1. Generally, the compensator will indeed trap a sufficient number of mobile ions to balance its charge. These ions can exchange, but they are quite well localized by the trap. 2. For incommensurate mobile-ion concentrations, the overall DC conductivity is decreased. 3. For commensurate concentrations, the DC conductivity can actually increase, as the trapping renders the remaining mobile-ion array effectively incommensurate.
UR - http://www.scopus.com/inward/record.url?scp=0020924883&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0020924883&partnerID=8YFLogxK
U2 - 10.1016/0167-2738(83)90172-8
DO - 10.1016/0167-2738(83)90172-8
M3 - Article
AN - SCOPUS:0020924883
VL - 9-10
SP - 1325
EP - 1332
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
IS - PART 2
ER -