{Sn[Zn4Sn4S17]}6-

A robust open framework based on metal-linked penta-supertetrahedral [Zn 4Sn4S17]10- clusters with ion-exchange properties

Manolis J. Manos, Ratnasabapathy G. Iyer, Eric Quarez, J. H. Liao, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

161 Citations (Scopus)

Abstract

(Chemical Equation Presented) Like zeolites, K6Sn[Zn 4Sn4S17] (see structure) has remarkable ion-exchange properties and forms CsK5Sn[Zn4Sn 4S17] and RbK5Sn[Zn4Sn 4S17] in the presence of the Cs+ and Rb + ions, respectively. These compounds have an open framework comprising [Zn4Sn4S17]10- clusters linked by Sn4+ centers and are remarkably stable. One-fifth of the K+ ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.

Original languageEnglish
Pages (from-to)3552-3555
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number23
DOIs
Publication statusPublished - Jun 6 2005

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Ion exchange
Metals
Ions
Zeolites

Keywords

  • Cluster compounds
  • Ion exchange
  • Nonlinear optics
  • Semiconductors
  • Zeolites

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

{Sn[Zn4Sn4S17]}6- : A robust open framework based on metal-linked penta-supertetrahedral [Zn 4Sn4S17]10- clusters with ion-exchange properties. / Manos, Manolis J.; Iyer, Ratnasabapathy G.; Quarez, Eric; Liao, J. H.; Kanatzidis, Mercouri G.

In: Angewandte Chemie - International Edition, Vol. 44, No. 23, 06.06.2005, p. 3552-3555.

Research output: Contribution to journalArticle

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AU - Liao, J. H.

AU - Kanatzidis, Mercouri G

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