Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols

Sara Abramovici; Ronny Neumann; Yoel Sasson

doi:10.1016/0304-5102(85)80037-7

Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols

Sara Abramovici, Ronny Neumann, Yoel Sasson

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.

Original language	English
Pages (from-to)	299-303
Number of pages	5
Journal	Journal of Molecular Catalysis
Volume	29
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(85)80037-7
Publication status	Published - 1985

ASJC Scopus subject areas

Engineering(all)

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abstract = "Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.",

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AU - Abramovici, Sara

AU - Neumann, Ronny

AU - Sasson, Yoel

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AB - Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.

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