Abstract
Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.
| Original language | English |
|---|---|
| Pages (from-to) | 299-303 |
| Number of pages | 5 |
| Journal | Journal of Molecular Catalysis |
| Volume | 29 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1985 |
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ASJC Scopus subject areas
- Engineering(all)
Cite this
Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols. / Abramovici, Sara; Neumann, Ronny; Sasson, Yoel.
In: Journal of Molecular Catalysis, Vol. 29, No. 3, 1985, p. 299-303.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols
AU - Abramovici, Sara
AU - Neumann, Ronny
AU - Sasson, Yoel
PY - 1985
Y1 - 1985
N2 - Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.
AB - Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.
UR - http://www.scopus.com/inward/record.url?scp=0022043058&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0022043058&partnerID=8YFLogxK
U2 - 10.1016/0304-5102(85)80037-7
DO - 10.1016/0304-5102(85)80037-7
M3 - Article
VL - 29
SP - 299
EP - 303
JO - Journal of Molecular Catalysis
JF - Journal of Molecular Catalysis
SN - 0304-5102
IS - 3
ER -