Solar water splitting cells

Michael G. Walter, Emily L. Warren, James R. McKone, Shannon W. Boettcher, Qixi Mi, Elizabeth A. Santori, Nathan S. Lewis

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Abstract

Water splitting cells with direct semiconductor/liquid contacts are attractive because they avoid significant fabrication and systems costs involved with the use of separate electrolyzers wired to p-n junction solar cells. Another attractive advantage of photoelectrochemical water splitting directly at the semiconductor surface is the ease with which an electric field can be created at a semiconductor/liquid junction. Water splitting cells require semiconductor materials that are able to support rapid charge transfer at a semiconductor/aqueous interface, that exhibit long-term stability, and that can efficiently harvest a large portion of the solar spectrum. In contrast to the use of a single band gap configuration (S2) to split water, the use of a dual band gap (D4) water splitting cell configuration, where the electric field is generated at a semiconductor liquid junction or through a buried junction, appears to be the most efficient and robust use of complementary light absorbing materials.

Original languageEnglish
Pages (from-to)6446-6473
Number of pages28
JournalChemical reviews
Volume110
Issue number11
DOIs
Publication statusPublished - Nov 10 2010

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ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010). Solar water splitting cells. Chemical reviews, 110(11), 6446-6473. https://doi.org/10.1021/cr1002326