Solid state polymerization of poly(phthalocyaninatosiloxane)

K. G. Beltsios, Tobin J Marks, S. H. Carr

Research output: Contribution to journal › Article

Abstract

A kinetic study of the solid state formation of poly(phthalocyaninatosiloxane) ([Si(Pc)O]n), a candidate component of air-stable, light-weight, electrically conductive fibers, was performed. The initiation of reaction occurs at defect sites, whereas propagation takes place through a "chain polycondensation" scheme as a result of lattice (topochemical) control. An Avrami-type power 2 law fits the low temperature data up to high conversions and the high temperature data up to the reaction rate maximum. The maximum chain length is probably controlled by the relative phthalocyanine ring spacings of the reactant and product lattices.

Original languageEnglish
Pages (from-to)31-35
Number of pages5
JournalSynthetic Metals
Volume29
Issue number2-3
DOIs
Publication statusPublished - Mar 21 1989

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polymerization
Polymerization
solid state
Polycondensation
Chain length
Polysilicon
Reaction rates
reaction kinetics
spacing
Temperature
Defects
Kinetics
fibers
propagation
Fibers
rings
air
defects
kinetics
products

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Solid state polymerization of poly(phthalocyaninatosiloxane). / Beltsios, K. G.; Marks, Tobin J; Carr, S. H.

In: Synthetic Metals, Vol. 29, No. 2-3, 21.03.1989, p. 31-35.

Research output: Contribution to journal › Article

Beltsios, KG, Marks, TJ & Carr, SH 1989, 'Solid state polymerization of poly(phthalocyaninatosiloxane)', Synthetic Metals, vol. 29, no. 2-3, pp. 31-35. https://doi.org/10.1016/0379-6779(89)90875-8
Beltsios KG, Marks TJ, Carr SH. Solid state polymerization of poly(phthalocyaninatosiloxane). Synthetic Metals. 1989 Mar 21;29(2-3):31-35. https://doi.org/10.1016/0379-6779(89)90875-8
Beltsios, K. G. ; Marks, Tobin J ; Carr, S. H. / Solid state polymerization of poly(phthalocyaninatosiloxane). In: Synthetic Metals. 1989 ; Vol. 29, No. 2-3. pp. 31-35.
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