Solvent-anchored supported liquid phase catalysis: Polyoxometalate-catalyzed oxidations

Ronny Neumann, M. Cohen

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

A new immobilization technique for homogeneous catalysts is represented by the title process. Polyethers that are covalently attached to silica surfaces (shown schematically on the right) act as solvent and/or ligands for the catalysts, in this case polyoxometalates (POM). Such systems allow, for example, the quantitative oxidation of cyclooctene to cyclooctene oxide. The catalyst can be recycled without loss of activity.

Original languageEnglish
Pages (from-to)1738-1740
Number of pages3
JournalAngewandte Chemie - International Edition
Volume36
Issue number16
Publication statusPublished - 1997

Fingerprint

Catalysis
Oxidation
Catalysts
Liquids
Polyethers
Silicon Dioxide
Oxides
Ligands
Silica
polyoxometalate I

Keywords

  • Heterogeneous catalysis
  • Homogeneous catalysis
  • Oxidations
  • Polyoxometalates

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Solvent-anchored supported liquid phase catalysis : Polyoxometalate-catalyzed oxidations. / Neumann, Ronny; Cohen, M.

In: Angewandte Chemie - International Edition, Vol. 36, No. 16, 1997, p. 1738-1740.

Research output: Contribution to journalArticle

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