Solvent and electrolyte effects on Ni(PR2N R′2)2-catalyzed electrochemical oxidation of hydrogen

Ryan M. Stolley, Jonathan M. Darmon, Monte L. Helm

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17 Citations (Scopus)


We report solvent and electrolyte effects on the electrocatalytic oxidation of H2 using Ni(PCy2NR′ 2)2 (R = Bn, tBu) complexes. A turnover frequency of 46 s-1 for Ni(PCy2N Bn2)2 was obtained using 0.2 M [ nBu4N][BF4] in THF. A turnover frequency of 51 s-1 was observed for Ni(PCy2N tBu2)2 using 0.2 M [nBu 4N][B(C6F5)4] in fluorobenzene. These observations, in conjunction with previous studies, indicate nitrile binding inhibits catalysis supported by Ni(PCy2N Bn2)2. This journal is

Original languageEnglish
Pages (from-to)3681-3684
Number of pages4
JournalChemical Communications
Issue number28
Publication statusPublished - Apr 11 2014


ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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