Solvent and electrolyte effects on Ni(PR2NR′2)2-catalyzed electrochemical oxidation of hydrogen

Ryan M. Stolley, Jonathan M. Darmon, Monte L. Helm

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

We report solvent and electrolyte effects on the electrocatalytic oxidation of H2 using Ni(PCy2NR′2)2 (R = Bn, tBu) complexes. A turnover frequency of 46 s−1 for Ni(PCy2NBn2)2 was obtained using 0.2 M [nBu4N][BF4] in THF. A turnover frequency of 51 s−1 was observed for Ni(PCy2NtBu2)2 using 0.2 M [nBu4N][B(C6F5)4] in fluorobenzene. These observations, in conjunction with previous studies, indicate nitrile binding inhibits catalysis supported by Ni(PCy2NBn2)2.

Original languageEnglish
Pages (from-to)3681-3684
Number of pages4
JournalChemical Communications
Volume50
Issue number28
DOIs
Publication statusPublished - Mar 11 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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