Abstract
Solvent-induced electronic effects exist for intervalence charge-transfer reactions involving complexes of the type (2,2′-bipyridine)2ClRuII(pyrazine)Ru III(NH3)4L4+, where L = NH3 or various pyrazyl, pyridyl, or polypyridyl ligands. Specifically the following are found: (1) Mixing between appropriate donor and acceptor metal orbitals can be influenced substantially by the nature of the solvent. (2) The metal-metal interaction energy, H13, is also affected. (3) From the solvent effects, intervalence transfer appears to follow (in part) a hole-transfer pathway.
| Original language | English |
|---|---|
| Pages (from-to) | 1563-1565 |
| Number of pages | 3 |
| Journal | Journal of the American Chemical Society |
| Volume | 112 |
| Issue number | 4 |
| Publication status | Published - Feb 14 1990 |
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ASJC Scopus subject areas
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Solvent control of orbital mixing and electronic coupling in Ligand-Bridged mixed-valence complexes : Evidence for an intervalence hole-transfer pathway. / Hupp, Joseph T.
In: Journal of the American Chemical Society, Vol. 112, No. 4, 14.02.1990, p. 1563-1565.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solvent control of orbital mixing and electronic coupling in Ligand-Bridged mixed-valence complexes
T2 - Evidence for an intervalence hole-transfer pathway
AU - Hupp, Joseph T
PY - 1990/2/14
Y1 - 1990/2/14
N2 - Solvent-induced electronic effects exist for intervalence charge-transfer reactions involving complexes of the type (2,2′-bipyridine)2ClRuII(pyrazine)Ru III(NH3)4L4+, where L = NH3 or various pyrazyl, pyridyl, or polypyridyl ligands. Specifically the following are found: (1) Mixing between appropriate donor and acceptor metal orbitals can be influenced substantially by the nature of the solvent. (2) The metal-metal interaction energy, H13, is also affected. (3) From the solvent effects, intervalence transfer appears to follow (in part) a hole-transfer pathway.
AB - Solvent-induced electronic effects exist for intervalence charge-transfer reactions involving complexes of the type (2,2′-bipyridine)2ClRuII(pyrazine)Ru III(NH3)4L4+, where L = NH3 or various pyrazyl, pyridyl, or polypyridyl ligands. Specifically the following are found: (1) Mixing between appropriate donor and acceptor metal orbitals can be influenced substantially by the nature of the solvent. (2) The metal-metal interaction energy, H13, is also affected. (3) From the solvent effects, intervalence transfer appears to follow (in part) a hole-transfer pathway.
UR - http://www.scopus.com/inward/record.url?scp=0011186588&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0011186588&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0011186588
VL - 112
SP - 1563
EP - 1565
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 4
ER -