Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4

A 1-D indium telluride

Zhen Chen, Jing Li, Feng Chen, Davide M. Proserpio

Research output: Contribution to journal › Article

35 Citations (Scopus)

Abstract

Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.

Original languageEnglish
Pages (from-to)255-258
Number of pages4
JournalInorganica Chimica Acta
Volume273
Issue number1-2
Publication statusPublished - May 15 1998

Fingerprint

ethylenediamine
indium tellurides
Indium
Crystal growth
Crystal structure
Positive ions
Single crystals
X ray diffraction
Crystals
tellurides
crystal structure
synthesis
Crystallization
Metals
X-Ray Diffraction
tetrahedrons
Cations
crystal growth
cations
Temperature

Keywords

  • Crystal structures
  • Solvothermal reactions
  • Tellurides

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4 : A 1-D indium telluride. / Chen, Zhen; Li, Jing; Chen, Feng; Proserpio, Davide M.

In: Inorganica Chimica Acta, Vol. 273, No. 1-2, 15.05.1998, p. 255-258.

Research output: Contribution to journal › Article

Chen, Z, Li, J, Chen, F & Proserpio, DM 1998, 'Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4: A 1-D indium telluride', Inorganica Chimica Acta, vol. 273, no. 1-2, pp. 255-258.
Chen Z, Li J, Chen F, Proserpio DM. Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4: A 1-D indium telluride. Inorganica Chimica Acta. 1998 May 15;273(1-2):255-258.
Chen, Zhen ; Li, Jing ; Chen, Feng ; Proserpio, Davide M. / Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4 : A 1-D indium telluride. In: Inorganica Chimica Acta. 1998 ; Vol. 273, No. 1-2. pp. 255-258.
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