Abstract
Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
| Original language | English |
|---|---|
| Pages (from-to) | 255-258 |
| Number of pages | 4 |
| Journal | Inorganica Chimica Acta |
| Volume | 273 |
| Issue number | 1-2 |
| Publication status | Published - May 15 1998 |
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Keywords
- Crystal structures
- Solvothermal reactions
- Tellurides
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4 : A 1-D indium telluride. / Chen, Zhen; Li, Jing; Chen, Feng; Proserpio, Davide M.
In: Inorganica Chimica Acta, Vol. 273, No. 1-2, 15.05.1998, p. 255-258.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4
T2 - A 1-D indium telluride
AU - Chen, Zhen
AU - Li, Jing
AU - Chen, Feng
AU - Proserpio, Davide M.
PY - 1998/5/15
Y1 - 1998/5/15
N2 - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
AB - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
KW - Crystal structures
KW - Solvothermal reactions
KW - Tellurides
UR - http://www.scopus.com/inward/record.url?scp=0000155843&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000155843&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0000155843
VL - 273
SP - 255
EP - 258
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1-2
ER -