TY - JOUR
T1 - Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4
T2 - A 1-D indium telluride
AU - Chen, Zhen
AU - Li, Jing
AU - Chen, Feng
AU - Proserpio, Davide M.
N1 - Funding Information:
Financial support from the National Science Fonndation (DMR-9553066) is greatly appreciated, Jl_, is also grateful 1o the donors of the Petroletun Research Fund (Type-B), administrated by the American Chemical Society and to the Rutgers University for the Research Council Grant. Assis-lallce from Ray Jones. the Universily Construction Manager, during the laboratory relloValJOl/is acknowledged.
PY - 1998/5/15
Y1 - 1998/5/15
N2 - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
AB - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
KW - Crystal structures
KW - Solvothermal reactions
KW - Tellurides
UR - http://www.scopus.com/inward/record.url?scp=0000155843&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000155843&partnerID=8YFLogxK
U2 - 10.1016/s0020-1693(97)06145-8
DO - 10.1016/s0020-1693(97)06145-8
M3 - Article
AN - SCOPUS:0000155843
VL - 273
SP - 255
EP - 258
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1-2
ER -