Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4: A 1-D indium telluride

Zhen Chen; Jing Li; Feng Chen; Davide M. Proserpio

doi:10.1016/s0020-1693(97)06145-8

Solvothermal synthesis and crystal structure of [La(ethylenediamine)₄Cl] In₂Te₄: A 1-D indium telluride

Zhen Chen, Jing Li, Feng Chen, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)₄Cl] In₂Te₄ (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In₂Te₄)^2-] built of InTe₄ tetrahedra sharing opposite edges, and [La(en)₄Cl]₂₊ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.

Original language	English
Pages (from-to)	255-258
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	273
Issue number	1-2
DOIs	https://doi.org/10.1016/s0020-1693(97)06145-8
Publication status	Published - May 15 1998

Keywords

Crystal structures
Solvothermal reactions
Tellurides

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4: A 1-D indium telluride",

abstract = "Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) {\AA}, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.",

keywords = "Crystal structures, Solvothermal reactions, Tellurides",

author = "Zhen Chen and Jing Li and Feng Chen and Proserpio, {Davide M.}",

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T1 - Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4

T2 - A 1-D indium telluride

AU - Chen, Zhen

AU - Li, Jing

AU - Chen, Feng

AU - Proserpio, Davide M.

PY - 1998/5/15

Y1 - 1998/5/15

N2 - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.

AB - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.

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KW - Solvothermal reactions

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