Abstract
Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in [La(ethylenediamine)4Cl] In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group 14 ( No. 79) a = 13.471 (3), c = 7.295 (3) Å, Z = 2.1 is a Zintl compound containing one-dimensional polymeric chains of 1 cursive Greek chi [(In2Te4)2-] built of InTe4 tetrahedra sharing opposite edges, and [La(en)4Cl]2+ (ethylenediamine = en) cations with regular monocapped squareantiprism nona-coordination.
| Original language | English |
|---|---|
| Pages (from-to) | 255-258 |
| Number of pages | 4 |
| Journal | Inorganica Chimica Acta |
| Volume | 273 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - May 15 1998 |
Keywords
- Crystal structures
- Solvothermal reactions
- Tellurides
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Chen, Z., Li, J., Chen, F., & Proserpio, D. M. (1998). Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl] In2Te4: A 1-D indium telluride. Inorganica Chimica Acta, 273(1-2), 255-258. https://doi.org/10.1016/s0020-1693(97)06145-8