Solvothermal Synthesis of Alkline Metal Selenides Cs2PdSe16 and Studies of Thermal Stabilities

Zhen Chen, Ru Ji Wang, Jing Li

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The solvothermal technique was used for the synthesis of Cs2PdSe16 and the crystal structure was determined by single crystal X-ray diffraction methods. Cs2PdSe16 crystallizes in the tetragonal, space group P4b2 with a=1. 260 1(2) nm, b=1. 260 1(2) nm, c=0. 704 4(1) nm, V=1. 118 5(3) nm3, Z= 2, R=0. 051 4, wR=Q. 099 1. The crystal structure consists of two dimensional layers of alternate layers of [CsPd(Se4)2]- and [CsSe8]+. DSC result indicates its decomposition temperature at 334 °C.

Original languageEnglish
Pages (from-to)1094
Number of pages1
JournalKao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume22
Issue number7
Publication statusPublished - Jul 2001

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Thermodynamic stability
Crystal structure
Metals
Single crystals
Decomposition
X ray diffraction
Temperature

Keywords

  • Crystal structure
  • Inorganic polymer
  • Metal selenides
  • Solvothermal technique

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "The solvothermal technique was used for the synthesis of Cs2PdSe16 and the crystal structure was determined by single crystal X-ray diffraction methods. Cs2PdSe16 crystallizes in the tetragonal, space group P4b2 with a=1. 260 1(2) nm, b=1. 260 1(2) nm, c=0. 704 4(1) nm, V=1. 118 5(3) nm3, Z= 2, R=0. 051 4, wR=Q. 099 1. The crystal structure consists of two dimensional layers of alternate layers of [CsPd(Se4)2]- and [CsSe8]+. DSC result indicates its decomposition temperature at 334 °C.",
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N2 - The solvothermal technique was used for the synthesis of Cs2PdSe16 and the crystal structure was determined by single crystal X-ray diffraction methods. Cs2PdSe16 crystallizes in the tetragonal, space group P4b2 with a=1. 260 1(2) nm, b=1. 260 1(2) nm, c=0. 704 4(1) nm, V=1. 118 5(3) nm3, Z= 2, R=0. 051 4, wR=Q. 099 1. The crystal structure consists of two dimensional layers of alternate layers of [CsPd(Se4)2]- and [CsSe8]+. DSC result indicates its decomposition temperature at 334 °C.

AB - The solvothermal technique was used for the synthesis of Cs2PdSe16 and the crystal structure was determined by single crystal X-ray diffraction methods. Cs2PdSe16 crystallizes in the tetragonal, space group P4b2 with a=1. 260 1(2) nm, b=1. 260 1(2) nm, c=0. 704 4(1) nm, V=1. 118 5(3) nm3, Z= 2, R=0. 051 4, wR=Q. 099 1. The crystal structure consists of two dimensional layers of alternate layers of [CsPd(Se4)2]- and [CsSe8]+. DSC result indicates its decomposition temperature at 334 °C.

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