Spectral behavior of hydrogen-bonded systems: Quasiparticle model

S. F. Fischer, G. L. Hofacker, Mark A Ratner

Research output: Contribution to journalArticle

152 Citations (Scopus)

Abstract

The spectral behavior of protons forming hydrogen bonds in a solid is investigated. The ionic defect H3O+ in the ice crystal is used as a basic model. Strong interaction with optical phonons (wagging vibrations) is considered to infinite order by construction of a quasiparticle analogous to the small polaron. We predict for the absorption profile a broad peak with some fine structure at the low-frequency side. Temperature dependence, red shifting, and mass dependence of the spectrum are discussed.

Original languageEnglish
Pages (from-to)1934-1947
Number of pages14
JournalJournal of Chemical Physics
Volume52
Issue number4
Publication statusPublished - 1970

Fingerprint

Gene Conversion
Ice
Phonons
Protons
Hydrogen
Hydrogen bonds
ice
phonons
fine structure
hydrogen bonds
low frequencies
vibration
Defects
temperature dependence
Crystals
protons
defects
hydrogen
profiles
crystals

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Spectral behavior of hydrogen-bonded systems : Quasiparticle model. / Fischer, S. F.; Hofacker, G. L.; Ratner, Mark A.

In: Journal of Chemical Physics, Vol. 52, No. 4, 1970, p. 1934-1947.

Research output: Contribution to journalArticle

Fischer, S. F. ; Hofacker, G. L. ; Ratner, Mark A. / Spectral behavior of hydrogen-bonded systems : Quasiparticle model. In: Journal of Chemical Physics. 1970 ; Vol. 52, No. 4. pp. 1934-1947.
@article{0f100e259a3d4a8e9eb76a0710a79ae3,
title = "Spectral behavior of hydrogen-bonded systems: Quasiparticle model",
abstract = "The spectral behavior of protons forming hydrogen bonds in a solid is investigated. The ionic defect H3O+ in the ice crystal is used as a basic model. Strong interaction with optical phonons (wagging vibrations) is considered to infinite order by construction of a quasiparticle analogous to the small polaron. We predict for the absorption profile a broad peak with some fine structure at the low-frequency side. Temperature dependence, red shifting, and mass dependence of the spectrum are discussed.",
author = "Fischer, {S. F.} and Hofacker, {G. L.} and Ratner, {Mark A}",
year = "1970",
language = "English",
volume = "52",
pages = "1934--1947",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "4",

}

TY - JOUR

T1 - Spectral behavior of hydrogen-bonded systems

T2 - Quasiparticle model

AU - Fischer, S. F.

AU - Hofacker, G. L.

AU - Ratner, Mark A

PY - 1970

Y1 - 1970

N2 - The spectral behavior of protons forming hydrogen bonds in a solid is investigated. The ionic defect H3O+ in the ice crystal is used as a basic model. Strong interaction with optical phonons (wagging vibrations) is considered to infinite order by construction of a quasiparticle analogous to the small polaron. We predict for the absorption profile a broad peak with some fine structure at the low-frequency side. Temperature dependence, red shifting, and mass dependence of the spectrum are discussed.

AB - The spectral behavior of protons forming hydrogen bonds in a solid is investigated. The ionic defect H3O+ in the ice crystal is used as a basic model. Strong interaction with optical phonons (wagging vibrations) is considered to infinite order by construction of a quasiparticle analogous to the small polaron. We predict for the absorption profile a broad peak with some fine structure at the low-frequency side. Temperature dependence, red shifting, and mass dependence of the spectrum are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0001519793&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001519793&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001519793

VL - 52

SP - 1934

EP - 1947

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 4

ER -